Bian Jiepeng, Zhao Qiuli, Hou Zhenzhong, Dong Jie, Yang Qinghao, Zhang Guanjun
College of Materials Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054, People's Republic of China.
State Key Laboratory of Electrical Insulation and Power Equipment, School of Electrical Engineering, Xi'an Jiaotong University, Xi'an 710049, People's Republic of China.
R Soc Open Sci. 2019 Jan 16;6(1):181509. doi: 10.1098/rsos.181509. eCollection 2019 Jan.
Polymer-based composites with the advantages of ceramics and polymers exhibit high dielectric constant, good processing properties and low dielectric loss. The composites with a varied content of irregular alumina (-AlO) filler were prepared by UV-cured epoxy acrylic (EA). Spherical alumina (-AlO) was used as a filler to further investigate the effect of alumina (AlO) shapes on dielectric properties of composites in the frequency range of 50 Hz-1 MHz. Fourier transform infrared spectroscopy proved that the UV-cured epoxy acrylic/alumina (AlO/EA) composites were successfully fabricated. Scanning electron microscopy demonstrated that -AlO particles have superior homodispersion in the matrix. Through testing, for all samples, with the addition of AlO, the relative permittivity of composites increased as expected, and the dielectric loss decreased accordingly. These data show that the incorporation of -AlO particles presents better properties when compared with -AlO/EA, which indicates that -AlO particles have more influence on the dielectric properties of the composites than those of -AlO particles. According to Weibull distribution, the characteristic breakdown strength of the AlO/EA composites was obtained and the results suggested that the composites of -AlO/EA exhibited better breakdown performance.
兼具陶瓷和聚合物优点的聚合物基复合材料具有高介电常数、良好的加工性能和低介电损耗。通过紫外光固化环氧丙烯酸酯(EA)制备了具有不同含量不规则氧化铝(-AlO)填料的复合材料。使用球形氧化铝(-AlO)作为填料,进一步研究了氧化铝(AlO)形状对50 Hz - 1 MHz频率范围内复合材料介电性能的影响。傅里叶变换红外光谱证明成功制备了紫外光固化环氧丙烯酸酯/氧化铝(AlO/EA)复合材料。扫描电子显微镜表明-AlO颗粒在基体中具有优异的均匀分散性。通过测试,对于所有样品,随着AlO的加入,复合材料的相对介电常数如预期增加,介电损耗相应降低。这些数据表明,与-AlO/EA相比,加入-AlO颗粒具有更好的性能,这表明-AlO颗粒对复合材料介电性能的影响比-AlO颗粒更大。根据威布尔分布,获得了AlO/EA复合材料的特征击穿强度,结果表明-AlO/EA复合材料表现出更好的击穿性能。