State Forestry Administration, Research Institute of Subtropical Forestry, Chinese Academy of Forestry, Hangzhou, P. R. China.
J Sci Food Agric. 2019 Aug 30;99(11):5000-5007. doi: 10.1002/jsfa.9740. Epub 2019 May 13.
The Maillard reaction products (MRPs) formed after roasting of oil-tea camellia seeds (camellia seeds) were investigated. Camellia seeds are inevitably heated during processing, but the effect of heating or roasting on the physicochemical properties of camellia seed or oil-tea camellia seed oil (camellia oil) has been seldom studied, especially with respect to the Maillard reaction.
Changes in reducing sugars, free amino acids, pH, color, browning intensity and MRP (furosine, glyoxal, methylglyoxal, 5-hydroxymethylfurfural and furural) concentrations were examined in camellia seeds during roasting at 120-160 °C for 20-120 min. Results showed that roasting leads first to a decrease and then to a considerable increase in free amino groups and, at the same time, to a reduction in moisture content and decrease in pH. The sucrose content of the seeds decreased, while that of glucose and fructose increased reciprocally during roasting. On the other hand, the observed changes concerning glyoxal were negligible. Furthermore, 5-hydroxymethylfurfural and furfural have been found at the end of the roasting process, with maximum values of 572.26 ± 1.91 mg kg dry wt and 0.46 ± 0.003 mg kg dry wt, at 160 °C for 120 min, respectively.
This investigation provides the initial groundwork necessary for the development and implementation of green and efficient technology that could be applied to obtain high-quality camellia oil. Future research is necessary to assess antioxidant capacity, quality and safety of oil after thermal processing of camellia seeds. © 2019 Society of Chemical Industry.
研究了油茶树种子(茶籽)烘烤后形成的美拉德反应产物(MRP)。茶籽在加工过程中不可避免地会受到加热,但加热或烘烤对茶籽或油茶籽油(茶油)理化性质的影响却很少被研究,特别是对美拉德反应的影响。
在 120-160°C 下烘烤 20-120 分钟期间,研究了茶籽在烘烤过程中还原糖、游离氨基酸、pH 值、颜色、褐变强度和 MRP(糠醛、乙二醛、甲基乙二醛、5-羟甲基糠醛和糠醛)浓度的变化。结果表明,烘烤首先导致游离氨基酸含量先减少后增加,同时水分含量减少,pH 值降低。种子中的蔗糖含量降低,而葡萄糖和果糖的含量在烘烤过程中相互增加。另一方面,观察到的乙二醛变化可以忽略不计。此外,在烘烤过程结束时发现了 5-羟甲基糠醛和糠醛,在 160°C 烘烤 120 分钟时,其含量分别达到最大值 572.26±1.91mg/kg 干重和 0.46±0.003mg/kg 干重。
这项研究为开发和实施绿色高效技术提供了必要的初步基础,该技术可应用于获得高质量的茶油。需要进一步研究评估茶籽热加工后油的抗氧化能力、质量和安全性。© 2019 化学工业协会。