Effect of Impregnation of Biodegradable Polyesters with Polyphenols from and Walnut Green Husk.

The publication describes a process combining the extraction of plant material and impregnation of biodegradable polymers (polylactide (PLA) and polyhydroxyalkanoate (PHA)). As raw plant materials for making extracts, and green walnut husk were selected due to their high content of active phytochemicals, including antioxidants. The extracts used to impregnate polymers contained valuable polyphenolic compounds, as confirmed by FTIR and UV-Vis spectroscopy. After impregnation, the polymer samples showed greater thermal stability, determined by the differential scanning calorimetry (DSC) method. In addition, despite the presence of natural antibacterial and antifungal substances in the extracts, the polyester samples remained biodegradable. The manuscript also describes the effect of UV aging on the change of surface free energy and the color of polymers. UV aging has been selected for testing due to the high susceptibility of plant compounds to this degrading factor. The combination of the extraction of plant material and polymer impregnation in one process proved to be an effective and functional method, as both the obtained plant extracts and impregnated polymers showed the expected properties.