Teasdale Ian
Institute of Polymer Chemistry Johannes Kepler University Linz Altenberger Straße 69 4040 Linz Austria.
Eur J Inorg Chem. 2019 Mar 31;2019(11-12):1445-1456. doi: 10.1002/ejic.201801077. Epub 2018 Dec 10.
This microreview details recent developments in stimuli-responsive polymers with phosphorus in the main-chain, in particular polyphosphazenes and polyphosphoesters. The presence of phosphorus in the polymers endows unique properties onto the macromolecules, which can be utilized for the preparation of materials capable of physically responding to specific stimuli. Achieving the desired responsiveness has been much facilitated by recent developments in synthetic polymer chemistry, in particular controlled synthesis and backbone functionalization phosphorus-based polymers, in order to achieve the required properties and hence responsiveness of the materials. The development of phosphorus-based polymers which respond to the most important stimuli are discussed, namely, pH, oxidation, reduction, temperature and biological triggers. The polymers are placed in the context not just of each other but also with reference to state-of-the-art organic polymers.
本微综述详细介绍了主链含磷的刺激响应性聚合物的最新进展，特别是聚磷腈和聚磷酸酯。聚合物中磷的存在赋予了大分子独特的性质，这些性质可用于制备能够对特定刺激产生物理响应的材料。合成聚合物化学的最新进展，特别是基于磷的聚合物的可控合成和主链功能化，极大地促进了所需响应性的实现，从而实现材料所需的性能和响应性。本文讨论了对最重要刺激作出响应的磷基聚合物的发展，即pH值、氧化、还原、温度和生物触发因素。这些聚合物不仅相互关联，而且还与最先进的有机聚合物相关联。
