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从苎麻韧皮中制备微纤维素和纳米纤维素纤维及其表征

Preparation and Characterization of Microcellulose and Nanocellulose Fibers from A V Bast.

作者信息

Nie Kai, Song Yan, Liu Shaoyang, Han Guangting, Ben Haoxi, Ragauskas Arthur J, Jiang Wei

机构信息

State Key Laboratory of Bio-Fibers and Eco-Textiles, Qingdao University, Qingdao, China.

College of Textile & Clothing, Qingdao University, Qingdao, China.

出版信息

Polymers (Basel). 2019 May 19;11(5):907. doi: 10.3390/polym11050907.

Abstract

Artemisia vulgaris is an economic plant that is spreading widely in central China. Its unused bast generates a large amount of biomass waste annually. Utilizing the fibers in Artemisia vulgaris bast may provide a new solution to this problem. This research attempts to strengthen the understanding of Artemisia vulgaris by analyzing its fiber compositions and preparing micro- and nano-cellulose fibers, which can be used as raw materials for composites. In this work, Artemisia vulgaris bast powder (AP) and microcellulose and nanocellulose fibers (AMFs and ANFs) were produced and characterized by optical microscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), thermogravimetric analysis (TG), and bacteriostatic test. The results indicated that cellulose, hemicellulose, and lignin were the main components in the Artemisia vulgaris bast. The cellulose content reached 40.9%. The Artemisia vulgaris single fibers were microcellulose fibers with an average length of 850.6 μm and a diameter of 14.4 μm. Moreover, the AMF had considerable antibacterial ability with an antibacterial ratio of 36.6%. The ANF showed a length range of 250-300 nm and a diameter of 10-20 nm, and it had a higher crystallinity (76%) and a lower thermal stability (initial degradation temperature of 183 °C) compared with raw ANF (233 °C). This study provides fundamental information on Artemisia vulgaris bast cellulose for its subsequent utilization.

摘要

艾蒿是一种在中国中部广泛分布的经济植物。其未被利用的韧皮每年会产生大量生物质废弃物。利用艾蒿韧皮中的纤维可能为解决这一问题提供新的方案。本研究试图通过分析其纤维组成并制备可作为复合材料原料的微纤维素和纳米纤维素纤维,来加强对艾蒿的了解。在这项工作中,制备了艾蒿韧皮粉末(AP)以及微纤维素和纳米纤维素纤维(AMF和ANF),并通过光学显微镜、透射电子显微镜(TEM)、X射线衍射(XRD)、热重分析(TG)和抑菌试验对其进行了表征。结果表明,纤维素、半纤维素和木质素是艾蒿韧皮的主要成分。纤维素含量达到40.9%。艾蒿单纤维为微纤维素纤维,平均长度为850.6μm,直径为14.4μm。此外,AMF具有相当的抗菌能力,抗菌率为36.6%。ANF的长度范围为250 - 300nm,直径为10 - 20nm,与未处理的ANF(初始降解温度为233℃)相比,其结晶度更高(76%),热稳定性更低(初始降解温度为183℃)。本研究为艾蒿韧皮纤维素的后续利用提供了基础信息。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0bc0/6572438/0c13310572f4/polymers-11-00907-g001.jpg

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