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多糖/聚乳酸复合材料的制备及性能表征。

Preparation and Characterization of Polysaccharide/Polylactic Acid Composite.

机构信息

National and Local Joint Engineering Research Center for Green Preparation Technology of Biobased Materials, Yunnan Minzu University, Kunming 650500, China.

出版信息

Molecules. 2019 Jun 3;24(11):2104. doi: 10.3390/molecules24112104.

Abstract

Polylactic acid (PLA) is limited in its application due to its high price, high brittleness and low glass-transition temperature. Modification methods are currently used to overcome these shortcomings. In this study, polysaccharide (BSP) was blended with PLA by a solvent method. DMA data showed that the BSP/PLA film had a higher glass-transition temperature, and the glass-transition temperature of the film showed an extreme value of 68 °C when the proportion of the chalk polysaccharide was 0.8%. TG data indicates that the composite film material has good thermal stability. Tensile tests show that the composite film is improved in rigidity and elasticity compared to the pure PLA film. The blending modification of PLA with white peony polysaccharide not only reduces the cost of PLA, but also improves the thermal and mechanical properties of PLA.

摘要

聚乳酸(PLA)由于价格高、脆性大、玻璃化转变温度低,其应用受到限制。目前采用改性方法来克服这些缺点。本研究采用溶剂法将多糖(BSP)与 PLA 共混。DMA 数据表明,BSP/PLA 薄膜具有较高的玻璃化转变温度,当壳聚糖多糖的比例为 0.8%时,薄膜的玻璃化转变温度表现出 68°C 的极值。TG 数据表明,该复合膜材料具有良好的热稳定性。拉伸试验表明,与纯 PLA 薄膜相比,复合薄膜在刚性和弹性方面均得到改善。白牡丹多糖对 PLA 的共混改性不仅降低了 PLA 的成本,而且改善了 PLA 的热学和力学性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29d1/6600352/8c00a2a5788c/molecules-24-02104-g001.jpg

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