Ahmadi B, Salimi S, Khorashad A S, Kheirandish F
Department of Physics, University of Kurdistan, P.O. Box 66177-15175, Sanandaj, Iran.
Sci Rep. 2019 Jun 19;9(1):8746. doi: 10.1038/s41598-019-45176-1.
Why do quantum evolutions occur and why do they stop at certain points? In classical thermodynamics affinity was introduced to predict in which direction an irreversible process proceeds. In this paper the quantum mechanical counterpart of the classical affinity is found. It is shown that the quantum version of affinity can predict in which direction a process evolves. A new version of the second law of thermodynamics is derived through quantum affinity for energy-incoherent state interconversion under thermal operations. we will also see that the quantum affinity can be a good candidate to be responsible, as a force, for driving the flow and backflow of information in Markovian and non-Markovian evolutions. Finally we show that the rate of quantum coherence can be interpreted as the pure quantum mechanical contribution of the total thermodynamic force and flow. Thus it is seen that, from a thermodynamic point of view, any interaction from the outside with the system or any measurement on the system may be represented by a quantum affinity.
量子演化为何会发生,又为何会在某些点停止?在经典热力学中,引入亲和势来预测不可逆过程的进行方向。本文找到了经典亲和势的量子力学对应物。结果表明,亲和势的量子版本可以预测过程的演化方向。通过热操作下能量非相干态相互转换的量子亲和势,推导出了热力学第二定律的一个新版本。我们还将看到,量子亲和势作为一种力,很可能是驱动马尔可夫和非马尔可夫演化中信息流和逆流的原因。最后我们表明,量子相干速率可以解释为总热力学力和流的纯量子力学贡献。因此可以看出,从热力学角度来看,系统与外界的任何相互作用或对系统的任何测量都可以用量子亲和势来表示。