重 13 族元素的 NO-和 NO 型二吡咯甲烷配合物的高效发光性能和阳离子识别能力。
Efficient luminescent properties and cation recognition ability of heavy group 13 element complexes of NO- and NO-type dipyrrins.
机构信息
Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS), University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan.
出版信息
Dalton Trans. 2019 Sep 21;48(35):13169-13175. doi: 10.1039/c9dt02403d. Epub 2019 Jul 11.
PMID:31292588
Abstract
The first mononuclear 1 : 1 complexes of heavy group 13 elements (Ga and In) and NO/NO-type dipyrrins were synthesized and characterized. The NO-type complexes showed efficient luminescent properties even in polar solvents. The NO-type complexes exhibited fluorometric responses to alkaline earth metal ions.
摘要
首次合成并表征了重主族 13 族元素（镓和铟）与 NO/NO 型二吡咯甲烷的单核 1:1 配合物。即使在极性溶剂中，NO 型配合物也表现出高效的发光性能。NO 型配合物对碱土金属离子表现出荧光响应。
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