Kawamura Yoko, Wada Takenari, Yamaguchi Miku, Mutsuga Motoh
National Institute of Health Sciences.
Tama Laboratory, Japan Food Research Laboratories.
Shokuhin Eiseigaku Zasshi. 2019;60(4):82-87. doi: 10.3358/shokueishi.60.82.
The Japanese Food Sanitation Act designates the evaporation residue test as a specification for plastics that intended to contact with foods. The test conditions and migration limits for oils and fatty foods were considered on the basis of the results obtained from the evaporation residue test according to the Japanese Act and the overall migration test into olive oil according to EN1186-2. The evaporation residue test was conducted using heptane at 25℃ for 1 hour. The results of most samples were under 30 μg/mL although those of high impact polystyrene,polymethylpentene and polyvinyl chloride were found to be over 30 μg/mL. However, these results were within the acceptable range of the relaxed limits (240, 120, 150 μg/mL). Regarding the overall migration into olive oil, most plastics were under the determination limit at 60℃ for 30 min. But the results for polyethylene, polypropylene and polyvinyl chloride were over 30 μg/mL at 95 and 121℃, which were higher than their evaporation residues. In other words, the existing test conditions and limits of the evaporation residue test could be used for testing plastics that come into contact with oils and fatty foods at lower temperatures. However, they are not adequate for evaluating some plastics that come into contact with oils and fatty foods at higher temperatures.
日本《食品卫生法》将蒸发残渣试验指定为与食品接触的塑料的一项规格标准。根据日本法规进行的蒸发残渣试验结果以及依据EN1186-2进行的向橄榄油中的全面迁移试验结果,对油脂类食品的试验条件和迁移限量进行了考量。蒸发残渣试验在25℃下用庚烷进行1小时。大多数样品的结果低于30μg/mL,不过发现高抗冲聚苯乙烯、聚甲基戊烯和聚氯乙烯的结果超过了30μg/mL。然而,这些结果在放宽限量(240、120、150μg/mL)的可接受范围内。关于向橄榄油中的全面迁移,大多数塑料在60℃下30分钟时低于测定限。但聚乙烯、聚丙烯和聚氯乙烯在95℃和121℃时的结果超过了30μg/mL,高于它们的蒸发残渣。换句话说,现有的蒸发残渣试验条件和限量可用于测试在较低温度下与油脂类食品接触的塑料。然而,它们不足以评估一些在较高温度下与油脂类食品接触的塑料。