Department of Engineering Science , The University of Electro-Communication , Chofu , Tokyo 182-8585 , Japan.
Inorg Chem. 2019 Oct 7;58(19):12733-12738. doi: 10.1021/acs.inorgchem.9b01342. Epub 2019 Sep 25.
We report here on the discovery of the superconductivity of a new ternary compound LaRhGa, which possesses a CaBeGe-type structure. Electrical resistivity and magnetic susceptibility measurements reveal that LaRhGa undergoes a superconducting transition at 3.7 K and exhibits type-II superconductivity. The -linear behavior of the upper critical field is likely induced by the two-gap superconducting state because of its structural features (i.e., its noncentrosymmetric structure). A transition at of specific heat suggested that the LaRhGa is a weak electron-phonon-mediated superconductor. Comparison with a related superconductor demonstrates that there is an important factor other than electron-phonon coupling strength that induces higher in the LaTMGa system with a noncentrosymmetric CaBeGe-type structure.
我们在此报告一种新的三元化合物 LaRhGa 的超导性的发现,它具有 CaBeGe 型结构。电阻率和磁化率测量表明,LaRhGa 在 3.7 K 下经历超导转变,并表现出 II 型超导性。上临界场的线性行为可能是由两个能隙超导态引起的,因为它的结构特征(即非中心对称结构)。比热的转变表明,LaRhGa 是一个弱电子-声子介导的超导体。与相关超导体的比较表明,在具有非中心对称 CaBeGe 型结构的 LaTMGa 体系中,除了电子-声子耦合强度之外,还有一个重要因素导致了更高的 。