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可持续环保型植物提取物介导的壳聚糖一锅法绿色回收。

Sustainable ecofriendly phytoextract mediated one pot green recovery of chitosan.

机构信息

Department of Environmental Health Science, Konkuk University, Seoul, 05029, South Korea.

Department of Chemistry, Thiruvalluvar University, Vellore, Tamil Nadu, 632115, India.

出版信息

Sci Rep. 2019 Sep 25;9(1):13832. doi: 10.1038/s41598-019-50133-z.

Abstract

Chitin and chitosan are biopolymers that have diverse applications in medicine, agriculture, food, cosmetics, pharmaceuticals, wastewater treatment and textiles. With bio-origins, they easily blend with biological systems and show exemplified compatibility which is mandatory when it comes to biomedical research. Chitin and chitosan are ecofriendly, however the processes that are used to recover them aren't ecofriendly. The focus of this work is to attempt an ecofriendly, sustainable phytomediated one pot recovery of chitosan from commercial chitin and from crab and shrimp shells and squid pen solid wastes. Graviola extracts have been employed, given the fact file that their active ingredients acetogenins actively interact with chitin in insects (resulting in its application as an insecticide). With that as the core idea, the graviola extracts were chosen for orchestrating chitin recovery and a possible chitin to chitosan transformation. The results confirm that graviola extracts did succeed in recovery of chitosan nanofibers from commercial chitin flakes and recovery of chitosan particles directly from solid marine wastes of crab, shrimp and squids. This is a first time report of a phyto-extract mediated novel chitosan synthesis method.

摘要

几丁质和壳聚糖是生物聚合物,在医学、农业、食品、化妆品、制药、废水处理和纺织品等领域有广泛的应用。由于其生物起源,它们很容易与生物系统融合,并表现出生物医学研究中必需的示例兼容性。几丁质和壳聚糖是环保的,但是用于回收它们的过程并不环保。这项工作的重点是尝试从商业几丁质、蟹虾壳和鱿鱼笔固体废物中进行环保、可持续的植物介导一锅法回收壳聚糖。使用了葛藤提取物,因为有事实表明,它们的活性成分乙酰氧基生素在昆虫中与几丁质积极相互作用(因此被用作杀虫剂)。基于这个核心思想,选择了葛藤提取物来协调几丁质的回收和可能的几丁质到壳聚糖的转化。结果证实,葛藤提取物确实成功地从商业几丁质薄片中回收了壳聚糖纳米纤维,并直接从蟹、虾和鱿鱼的海洋固体废物中回收了壳聚糖颗粒。这是首次报道植物提取物介导的新型壳聚糖合成方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/6761131/e6cfa34d7f7b/41598_2019_50133_Fig1_HTML.jpg

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