Leiva Jorge A, Wilson P Chris, Albano Joseph P, Nkedi-Kizza Peter, O'Connor George A
Programa de Posgrado en Ciencias Agrícolas y Recursos Naturales, Facultad de Ciencias Agroalimentarias, Ciudad Universitaria Rodrigo Facio, Universidad de Costa Rica, San José 11503, Costa Rica.
Institute of Food and Agricultural Sciences, Soil and Water Sciences Department, University of Florida, 2181 McCarty Hall A, P.O. Box 110290, Gainesville, Florida 32611, United States.
ACS Omega. 2019 Oct 15;4(18):17782-17790. doi: 10.1021/acsomega.9b02296. eCollection 2019 Oct 29.
Commercial producers of containerized ornamental plants almost exclusively use soilless media as the substrate for growing the plants. Soilless media are composed primarily of organic materials as opposed to mineral soils. Significant amounts of pesticides can leach from pots containing soilless media to which pesticides have been added as drenches or top-dressings. One of the goals of this project was to identify whether individual components comprising soilless media have differing affinities for the pesticides acephate, imidacloprid, metalaxyl, and plant growth regulator paclobutrazol. One-point 24 h equilibrium sorption assays were conducted to characterize sorption of the pesticides to sand, perlite, vermiculite, coir, peat, pine bark, and aluminum-water treatment residuals (Al-WTRs). Five-point isotherms were then constructed for the more sorptive peat and pine bark substrate components, and for the Al-WTRs. Results indicated significant differences in pesticide behavior with each substrate. Sorption of acephate to most of the substrate components was relatively low, comprising 21-31% of the initial amounts for soilless media components and 63% in Al-WTRs. Al-WTRs were highly sorptive for imidacloprid as evidenced by a partition coefficient of = 3275.4 L kg. Pine bark was the most sorptive for metalaxyl-M with a measured = 195.0 L kg. Peat had the highest affinity for paclobutrazol ( = 398.4 L kg). These results indicate that none of component of soilless media has a universally high attraction for all of the pesticides studied.
集装箱化观赏植物的商业生产者几乎完全使用无土介质作为植物生长的基质。无土介质主要由有机材料组成,与矿质土壤不同。大量农药会从添加了农药作为灌根剂或追肥的无土介质花盆中淋溶出来。本项目的目标之一是确定构成无土介质的各个成分对农药乙酰甲胺磷、吡虫啉、甲霜灵和植物生长调节剂多效唑是否具有不同的亲和力。进行了1.24小时平衡吸附试验,以表征农药在沙子、珍珠岩、蛭石、椰壳纤维、泥炭、松树皮和铝水处理残渣(Al-WTRs)上的吸附情况。然后针对吸附性更强的泥炭和松树皮基质成分以及Al-WTRs构建了五点等温线。结果表明,每种基质上农药的行为存在显著差异。乙酰甲胺磷在大多数基质成分上的吸附相对较低,占无土介质成分初始量的21%-31%,在Al-WTRs中为63%。Al-WTRs对吡虫啉具有高度吸附性,分配系数为 = 3275.4 L/kg可证明这一点。松树皮对甲霜灵-M的吸附性最强,测量值为 = 195.0 L/kg。泥炭对多效唑的亲和力最高( = 398.4 L/kg)。这些结果表明,无土介质的任何成分对所有研究的农药都没有普遍的高吸附性。