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车前草种胶作为新型水胶体的流变性能依赖于一价和二价盐。

The dependency of rheological properties of Plantago lanceolata seed mucilage as a novel source of hydrocolloid on mono- and di-valent salts.

机构信息

Department of Food Processing, Research Institute of Food Science and Technology, Mashhad, Iran.

University of Copenhagen, Department of Food Science, Rolighedsvej 30, DK-1958 Copenhagen, Denmark.

出版信息

Int J Biol Macromol. 2020 Mar 15;147:1278-1284. doi: 10.1016/j.ijbiomac.2019.10.093. Epub 2019 Nov 18.

Abstract

The effects of NaCl and CaCl (0-200 mM) on the rheological properties of Plantago lanceolata seed mucilage (PLSM) as a novel potential source of polysaccharide gum were investigated in this study. Furthermore, FTIR analysis was measured to supply more structural information. The FTIR spectra revealed that PLSM with the presence of glycoside bonds and carboxyl and hydroxyl groups behave like a typical polyelectrolyte. It was observed that the gum solutions exhibited viscoelastic properties under the given conditions and the addition of salts had significant affection on the rheological parameters of gum solutions. The weak gel-like behavior (0.1 < tan δ < 1) observed for all solutions at different ion types and ionic strengths. The limiting values of strain mostly increased with enhance cation concentration due to the intermolecular interaction and therefore increase the stiffness of gum solutions in the concentrated domain. The frequency sweep results showed that developing ion concentration had a positive effect on the viscoelasticity of gum solutions which Ca was more effective than Na. Tanglertpaibul&Rao model showed the highest efficiency to evaluate the intrinsic viscosity of PLSM for all co-solutes. The results of this study could be useful when considering the effects of salts on food systems.

摘要

本研究考察了 NaCl 和 CaCl(0-200 mM)对车前草种胶(PLSM)流变性能的影响,车前草种胶是一种新型多糖胶的潜在来源。此外,还进行了 FTIR 分析以提供更多的结构信息。FTIR 光谱表明,具有糖苷键和羧基及羟基的 PLSM 表现出典型的聚电解质行为。结果表明,在所给条件下,胶溶液表现出粘弹性,盐的添加对胶溶液的流变参数有显著影响。所有溶液在不同离子类型和离子强度下均表现出弱凝胶状行为(0.1<tanδ<1)。由于分子间相互作用,限制应变值随着阳离子浓度的增加而增加,因此在浓缩区增加了胶溶液的刚性。频率扫描结果表明,随着离子浓度的增加,胶溶液的粘弹性呈正相关,而 Ca 的效果优于 Na。Tanglertpaibul&Rao 模型在所有共溶剂中对 PLSM 特性粘度的评价效率最高。当考虑盐对食品体系的影响时,本研究结果可能具有参考价值。

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