National Centre of Excellence in Analytical Chemistry, University of Sindh, amshoro, Pakistan.
Institute of Microengineering and Nanoelectronics, University Kebangsaan Malaysia, Bangi, Malaysia.
Environ Sci Pollut Res Int. 2020 Mar;27(9):9970-9978. doi: 10.1007/s11356-019-07548-y. Epub 2020 Jan 13.
In this study, nano-sized ITO supported Pt-Pd bimetallic catalyst was synthesized for the degradation of methyl parathion pesticide, a common extremely toxic contaminant in aqueous solution. On the characterization with different techniques, a beautiful scenario of honeycomb architecture composed of ultra-small nanoneedles or fine hairs was found. Average size of nanocatalyst also confirmed which was in the range of 3-5 nm. High percent degradation (94%) was obtained in 30 s using 1.5 × 10 mg of synthesized nanocatalyst, 0.5 mM NaBH, and 110 W microwave radiations power. Recyclability of nanocatalyst was efficient till 4th cycle observed during study of reusability. The supported Pt-Pd bimetallic nanocatalyst on ITO displayed many advantages over conventional methods for degradation of methyl parathion pesticide, such as high percent degradation, short reaction time, small amount of nanocatalyst, and multitime reusability. Graphical abstract Schematic illustration of reaction for degradation of methyl parathion.
在这项研究中,合成了负载于纳米氧化铟锡(ITO)上的铂钯双金属纳米催化剂,用于降解水中常见的剧毒污染物甲基对硫磷农药。通过不同技术的表征,发现了一种由超小纳米针或细毛组成的美丽蜂窝状结构。纳米催化剂的平均尺寸也得到了确认,范围在 3-5nm 之间。在使用 1.5×10mg 合成纳米催化剂、0.5mM 硼氢化钠和 110W 微波辐射功率的情况下,在 30s 内即可获得 94%的高降解率。在可重复使用性研究中,观察到纳米催化剂在第 4 个循环时仍具有高效的可回收性。与传统的甲基对硫磷农药降解方法相比,负载于 ITO 的 Pt-Pd 双金属纳米催化剂具有许多优势,如高降解率、短反应时间、少量纳米催化剂和多次可重复使用性。