Kim Yong-Ho, Yoo Hyo-Sang, Son Hyeon-Taek
EV Components & Materials Group, Korea Institute of Industrial Technology, 1110-9 Oryong-dong, Buk-gu, Gwangju 61012, Republic of Korea.
J Nanosci Nanotechnol. 2020 Jul 1;20(7):4248-4252. doi: 10.1166/jnn.2020.17576.
In this research, effects of Zn and Cu content on microstructure, mechanical properties, electric and thermal conductivity of the as-extruded Al-(Zn+0.5Cu) alloys were investigated. As the content of Zn and Cu increased, the area ratio of Al₂Cu intermetallic compounds increased. After homogenization treatment and extrusion process, most of Al₂Cu intermetallic compounds was disappeared due to solution in Al matrix of Cu atoms. As the (Zn+0.5Cu) content increased from 1 to 2 wt.%, the average grain size decreased remarkably from 645 to 227 m due to the dynamic recrystallization caused by the solute Zn and Cu atoms during the extrusion. With increasing Zn and Cu additions, the thermal conductivity was decreased from 225 ( = 1) to 208 ( = 2) and 183 W/mK ( = 4) due to electric scattering by solute Zn and Cu atoms. The ultimate tensile strength (UTS) of the as-extruded Al-(1Zn+0.5Cu) alloys improved remarkably from 77 ( = 1) to 142 MPa ( = 4) as Zn and Cu content increased, and the elongation increased from 30 to 33%. This improvement in the strength resulted from the grain refinement and solid solution strengthening due to the solute Zn and Cu atoms. The Zn and Cu addition in Al alloy played an important role in thermal conductivity and mechanical properties.
在本研究中,研究了锌和铜含量对挤压态Al-(Zn+0.5Cu)合金的微观结构、力学性能、电导率和热导率的影响。随着锌和铜含量的增加,Al₂Cu金属间化合物的面积比增大。经过均匀化处理和挤压工艺后,由于铜原子溶解在铝基体中,大部分Al₂Cu金属间化合物消失。当(Zn+0.5Cu)含量从1 wt.%增加到2 wt.%时,由于挤压过程中溶质锌和铜原子引起的动态再结晶,平均晶粒尺寸从645μm显著减小到227μm。随着锌和铜添加量的增加,由于溶质锌和铜原子引起的电子散射,热导率从225(=1)降至208(=2)和183W/(m·K)(=4)。随着锌和铜含量的增加,挤压态Al-(1Zn+0.5Cu)合金的极限抗拉强度(UTS)从77(=1)显著提高到142MPa(=4),伸长率从30%增加到33%。强度的提高源于溶质锌和铜原子引起的晶粒细化和固溶强化。铝合金中添加锌和铜对热导率和力学性能起着重要作用。