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一种基于无金属碳设计的简便策略,用于深入了解液相碳催化的活性位点。

A facile strategy based on the metal-free design of carbon to deliver an insight into the active sites for liquid phase carbocatalysis.

作者信息

Wu Shuchang, Pan Xiaoli, Xu Shutao, Lin Yangming, Yan Hua, Wen Guodong, Diao Jiangyong, Liu Hongyang

机构信息

School of Pharmaceutical and Materials Engineering, Taizhou University, Taizhou 318000, Zhejiang Province, P. R. China.

出版信息

Chem Commun (Camb). 2020 Apr 4;56(26):3789-3792. doi: 10.1039/c9cc09918b. Epub 2020 Mar 4.

Abstract

An effective method to study the active sites for carbocatalysis is proposed based on designing a carbon catalyst in the absence of metal as the growth catalyst. The results suggest that the oxygenated groups on the aromatic carbons are mainly responsible for the catalytic reduction of nitrobenzene and some other reactions.

摘要

基于在没有金属作为生长催化剂的情况下设计碳催化剂,提出了一种研究碳催化活性位点的有效方法。结果表明,芳族碳上的含氧基团主要负责硝基苯的催化还原及其他一些反应。

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