Chemistry department, Faculty of Science, Cairo University, Giza 12613, Egypt.
Chemistry department, Faculty of Science, Taibah University, Medinah 30002, Saudi Arabia.
Molecules. 2020 Apr 2;25(7):1640. doi: 10.3390/molecules25071640.
LaSrFeO perovskite, prepared by the microwave-assisted method, was capped with cetyl trimethyl ammonium bromide (CTAB) cationic surfactant, and applied as a sorbent for the removal of the anionic Congo red (CR) dye from aqueous solutions. X-ray diffraction (XRD) patterns showed that the perovskite structure was not affected by capping; however, the particle size increased. There was a hipsochromic shift in the value of λ of the CR absorption spectrum in the presence of CTAB, which indicated the formation of an oppositely charged dye-surfactant complex. The adsorption efficiency of CTAB-capped LaSrFeO was independent of the pH of the solution-equilibrium was reached after a few minutes. The value of the maximum adsorption capacity, , was 151.52 mg.g, which was 10-times higher than that of the pure perovskite. The proposed sorbent maintained its excellent sorption ability in the presence of the sample matrix; therefore, it can be regenerated and reused with unchanged performance.
采用微波辅助法制备的 LaSrFeO 钙钛矿用十六烷基三甲基溴化铵(CTAB)阳离子表面活性剂进行封端,用作从水溶液中去除阴离子刚果红(CR)染料的吸附剂。X 射线衍射(XRD)图谱表明,钙钛矿结构不受封端影响,但粒径增大。在 CTAB 的存在下,CR 吸收光谱的 λ 值发生红移,这表明形成了带相反电荷的染料-表面活性剂配合物。CTAB 封端 LaSrFeO 的吸附效率与溶液的 pH 值无关-几分钟后即可达到平衡。最大吸附容量的值为 151.52mg.g,比纯钙钛矿高 10 倍。该吸附剂在存在样品基质的情况下仍保持优异的吸附能力,因此可以进行再生和重复使用,性能不变。