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十六烷基三甲基溴化铵修饰的 LaSrFeO 钙钛矿对工业过程中有机污染物的吸附性能。

The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped LaSrFeO Perovskite for Organic Pollutants from Industrial Processes.

机构信息

Chemistry department, Faculty of Science, Cairo University, Giza 12613, Egypt.

Chemistry department, Faculty of Science, Taibah University, Medinah 30002, Saudi Arabia.

出版信息

Molecules. 2020 Apr 2;25(7):1640. doi: 10.3390/molecules25071640.

Abstract

LaSrFeO perovskite, prepared by the microwave-assisted method, was capped with cetyl trimethyl ammonium bromide (CTAB) cationic surfactant, and applied as a sorbent for the removal of the anionic Congo red (CR) dye from aqueous solutions. X-ray diffraction (XRD) patterns showed that the perovskite structure was not affected by capping; however, the particle size increased. There was a hipsochromic shift in the value of λ of the CR absorption spectrum in the presence of CTAB, which indicated the formation of an oppositely charged dye-surfactant complex. The adsorption efficiency of CTAB-capped LaSrFeO was independent of the pH of the solution-equilibrium was reached after a few minutes. The value of the maximum adsorption capacity, , was 151.52 mg.g, which was 10-times higher than that of the pure perovskite. The proposed sorbent maintained its excellent sorption ability in the presence of the sample matrix; therefore, it can be regenerated and reused with unchanged performance.

摘要

采用微波辅助法制备的 LaSrFeO 钙钛矿用十六烷基三甲基溴化铵(CTAB)阳离子表面活性剂进行封端,用作从水溶液中去除阴离子刚果红(CR)染料的吸附剂。X 射线衍射(XRD)图谱表明,钙钛矿结构不受封端影响,但粒径增大。在 CTAB 的存在下,CR 吸收光谱的 λ 值发生红移,这表明形成了带相反电荷的染料-表面活性剂配合物。CTAB 封端 LaSrFeO 的吸附效率与溶液的 pH 值无关-几分钟后即可达到平衡。最大吸附容量的值为 151.52mg.g,比纯钙钛矿高 10 倍。该吸附剂在存在样品基质的情况下仍保持优异的吸附能力,因此可以进行再生和重复使用,性能不变。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b551/7180810/c7daf0a761b7/molecules-25-01640-g001a.jpg

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