Pyrolysis of fatty acids derived from hydrolysis of brown grease with biosolids.

The escalating generation of biosolids and increasing regulations regarding their safe handling and disposal have created a great environmental challenge. Recently, biosolids have been incorporated into the hydrolysis step of a two-step thermal lipid conversion process to act as water replacement in the production of renewable chemicals and fuels. Here, the hexane extract recovered from hydrolysis of biosolids, lipids from brown grease hydrolyzed using either water (control) or biosolids as a water replacement, was pyrolyzed at 410-450 °C for 2 h. The product distribution and composition were not significantly different when biosolids were used to hydrolyze brown grease instead of water. The liquid product consisted mainly of alkanes, alkenes, aromatics, and cyclic compounds similar to those in petroleum-derived liquid fuels. However, the use of biosolids as a water substitute resulted in a significant increase in sulphur content of the pyrolysate, which will necessitate processes to reduce the sulphur content before or after pyrolysis. Nevertheless, the pathways proposed in this paper are considered as potentially economically viable approaches to not only resolve the issues associated with disposal of biosolids but also to produce renewable hydrocarbons for fuel and chemical applications. Graphical abstract.