Dian Longyang, Marek Ilan
Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa, 3200009, Israel.
Org Lett. 2020 Jun 19;22(12):4914-4918. doi: 10.1021/acs.orglett.0c01833. Epub 2020 Jun 7.
A mild diastereoselective and enantioselective cobalt-catalyzed hydrosilylation reaction of achiral cyclopropenes has been developed. In this protocol, various substituted cyclopropenes and arylsilanes were transformed, in the presence of readily available chiral cobalt complex, into silylcyclopropanes with high selectivities.
已开发出一种温和的非对映选择性和对映选择性钴催化的非手性环丙烯的硅氢化反应。在此方法中，在易于获得的手性钴配合物存在下，各种取代的环丙烯和芳基硅烷以高选择性转化为硅基环丙烷。
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