Heyer Markus, Berkefeld André, Voepel Pascal, Milow Barbara
Institute of Materials Research, German Aerospace Center, Linder Hoehe, 51147 Cologne, Germany.
Materials (Basel). 2020 Jun 12;13(12):2677. doi: 10.3390/ma13122677.
Within this study, monolithic three-dimensional silica aerogel (SA) composite parts with super insulating properties are presented. A generic part based on fiber-reinforced (FR) silica aerogel for thermal insulation of the exhaust tubing system-to keep the exhaust gases as hot as possible to improve the efficiency of the catalyst system-was produced via a sol-gel-based molding process in combination with a supercritical drying using scCO. A thermal conductivity of 16 mW m K was measured via a heat flow meter technique. In this manuscript, we present a full cycle of the material compound design, starting with fundamental material evaluation including aerogel optimization, opacifier influence, and casting process. The obtained generic part in shape of a half-shell for pipe insulation is characterized under real conditions.
在本研究中,展示了具有超级绝缘性能的整体式三维二氧化硅气凝胶(SA)复合部件。基于纤维增强(FR)二氧化硅气凝胶的用于排气管系统隔热的通用部件——为使废气尽可能保持高温以提高催化系统的效率——是通过基于溶胶-凝胶的成型工艺结合使用超临界二氧化碳(scCO₂)的超临界干燥生产的。通过热流计技术测得热导率为16 mW/(m·K)。在本手稿中,我们展示了材料复合设计的完整流程,从包括气凝胶优化、遮光剂影响和铸造工艺在内的基础材料评估开始。所获得的用于管道隔热的半壳形状的通用部件在实际条件下进行了表征。