Cheng Yuan, Wang Juntong, Chi Yuan, Ma Zihong, Geng Xuhao, Chi Yujie
College of Food Science, Northeast Agricultural University, Harbin, China.
College of Food Science, Heilongjiang Bayi Agricultural University, Daqing, China.
J Sci Food Agric. 2021 Jan 30;101(2):433-440. doi: 10.1002/jsfa.10652. Epub 2020 Aug 21.
Dry heat processing remains the most promising and simple approach for achieving better gelling properties of spray-dried egg white powder (EWP). Water mobility and intermolecular interactions in gels derived from EWP were investigated after subjecting EWP to various dry heating times (0-21 days).
The gel hardness and water-holding capacity significantly increased with an increase in dry heating time (P < 0.05), and both parameters were positively correlated with gel transparency. In contrast to the coarser structure of untreated EWP gel, the gel of EWP corresponding to 15 days of dry heating time had a fine-stranded and orderly network structure with smaller pores. An increase in the binding force between the gel and water was observed with an increase in dry heating time due to the formation of more 'protein-water' hydrogen bonds. Increasing the dry heating time resulted in an increase in the contribution of disulfide bonds, which in turn made a significant contribution to the rigidity of the EWP gels. By contrast, a decrease in the contribution of ionic bonds and hydrophobic interactions upon increasing the dry heating time promoted the formation of orderly networks.
Overall, gel corresponding to EWP dry heating for 15 days had better gel properties, the highest transparency and water-holding capacity, as well as a fine-stranded and orderly network structure. These results provide more information on improvement of the gel properties of EWP through dry heat treatment. © 2020 Society of Chemical Industry.
干热处理仍然是实现喷雾干燥蛋清粉(EWP)更好凝胶特性的最具前景且简单的方法。在将EWP进行不同时长(0 - 21天)的干热处理后,研究了EWP凝胶中的水流动性和分子间相互作用。
凝胶硬度和持水能力随干热处理时间的增加而显著提高(P < 0.05),且这两个参数均与凝胶透明度呈正相关。与未处理的EWP凝胶较粗糙的结构相比,经过15天干热处理的EWP凝胶具有细链状且有序的网络结构,孔隙较小。由于形成了更多的“蛋白质 - 水”氢键,随着干热处理时间的增加,观察到凝胶与水之间的结合力增强。干热处理时间的增加导致二硫键的贡献增加,这反过来又对EWP凝胶的刚性做出了显著贡献。相比之下,随着干热处理时间的增加,离子键和疏水相互作用的贡献减少,促进了有序网络的形成。
总体而言,对应于EWP干热处理15天的凝胶具有更好的凝胶特性、最高的透明度和持水能力,以及细链状且有序的网络结构。这些结果为通过干热处理改善EWP凝胶特性提供了更多信息。© 2020化学工业协会。