School of Materials Engineering, Purdue University, 701 West Stadium Ave., ARMS, West Lafayette, IN, 47907-2045, USA.
Forest Products Laboratory, United States Forest Service, Madison, WI, 53726, USA.
Adv Mater. 2021 Jul;33(28):e2000718. doi: 10.1002/adma.202000718. Epub 2020 Jul 21.
Cellulose nanomaterials (CNMs) are a class of materials that have recently garnered attention in fields as varied as structural materials, biomaterials, rheology modifiers, construction, paper enhancement, and others. As the principal structural reinforcement of biomass giving wood its mechanical properties, CNM is strong and stiff, but also nontoxic, biodegradable, and sustainable with a very large (Gton yr ) source. Unfortunately, due to the relatively young nature of the field and inherent incompatibility of CNM with most man-made materials in use today, research has tended to be more basic-science oriented rather than commercially applicable, so there are few CNM-enabled products on the market today. Herein, efforts are presented for preparing and forming cellulose nanomaterial nanocomposites. The focus is on recent efforts attempting to mitigate common impediments to practical commercialization but is also placed in context with traditional efforts. The work is presented in terms of the progress made, and still to be made, on solving the most pressing challenges-getting properties that are competitive with currently used materials, removing organic solvent, solving the inherent incompatibility between CNM and polymers of interest, and incorporation into commonly used industrial processing techniques.
纤维素纳米材料(CNMs)是一类最近在结构材料、生物材料、流变改性剂、建筑、纸张增强等领域引起关注的材料。作为生物质的主要结构增强材料,赋予木材机械性能的纤维素纳米材料具有高强度和高刚性,但同时也具有无毒、可生物降解和可持续性,其来源非常丰富(Gton yr)。不幸的是,由于该领域相对较年轻,以及纤维素纳米材料与当今大多数人造材料之间固有的不兼容性,研究往往更侧重于基础科学,而不是商业应用,因此目前市场上很少有基于纤维素纳米材料的产品。本文介绍了制备和成型纤维素纳米材料纳米复合材料的努力。重点是最近试图减轻实际商业化常见障碍的努力,但也将其置于传统努力的背景下。本文根据解决最紧迫挑战的进展情况进行介绍,这些挑战包括获得具有竞争力的性能、去除有机溶剂、解决纤维素纳米材料与感兴趣的聚合物之间的固有不兼容性,以及纳入常用的工业加工技术。