de Mendonça Neuba Lucas, Pereira Junio Raí Felipe, Ribeiro Matheus Pereira, Souza Andressa Teixeira, de Sousa Lima Eduardo, Garcia Filho Fábio da Costa, Figueiredo André Ben-Hur da Silva, Braga Fábio de Oliveira, Azevedo Afonso Rangel Garcez de, Monteiro Sergio Neves
Department of Materials Science, Military Institute of Engineering-IME, Rio de Janeiro 22290270, Brazil.
Department of Mechanical and Aerospace Engineering, University of California San Diego-UCSD, La Jolla, CA 92093, USA.
Polymers (Basel). 2020 Aug 8;12(8):1776. doi: 10.3390/polym12081776.
Composites reinforced with natural lignocellulosic fibers (NLFs) are gaining relevance as the worldwide demand for renewable and sustainable materials increases. To develop novel natural composites with satisfactory properties, less common NLFs should also be investigated. Among these, the (CM), a type of sedge fiber, is already used in simple items like ropes, furniture, and paper, but has not yet been investigated as composite reinforcement for possible engineering applications. Therefore, the present work evaluated for the first time the properties of novel epoxy composites incorporated with 10, 20, and 30 vol.% of CM sedge fibers. Tensile, Izod-impact, and ballistic impact tests were performed, as well as Fourier transform infrared (FT-IR) spectroscopy and thermal analysis of the composites. Results disclosed a decrease (-55%) in tensile strengths as compared to the neat epoxy. However, the elastic modulus of the 30 vol.% sedge fiber composite increased (+127%). The total strain and absorbed ballistic energy did not show significant variation. The Izod impact energy of the 30 vol.% composite was found to be 181% higher than the values obtained for the neat epoxy as a control sample. An increase in both stiffness and toughness characterized a reinforcement effect of the sedge fiber. The thermal analysis revealed a slight decrease (-15%) in the degradation temperature of the CM sedge fiber composites compared to the neat epoxy. The glass-transition temperatures were determined to be in the range of 67 to 81 °C.
随着全球对可再生和可持续材料的需求增加,天然木质纤维素纤维(NLFs)增强的复合材料正变得越来越重要。为了开发具有令人满意性能的新型天然复合材料,还应研究不太常见的NLFs。其中,香蒲纤维(CM),一种莎草纤维,已被用于绳索、家具和纸张等简单物品中,但尚未作为可能的工程应用的复合材料增强材料进行研究。因此,本工作首次评估了掺入10%、20%和30%体积分数的香蒲纤维的新型环氧复合材料的性能。进行了拉伸、悬臂梁冲击和弹道冲击试验,以及复合材料的傅里叶变换红外(FT-IR)光谱和热分析。结果表明,与纯环氧树脂相比,拉伸强度降低了(-55%)。然而,30%体积分数的莎草纤维复合材料的弹性模量增加了(+127%)。总应变和吸收的弹道能量没有显示出显著变化。发现30%体积分数的复合材料的悬臂梁冲击能量比作为对照样品的纯环氧树脂获得的值高181%。刚度和韧性的增加表征了莎草纤维的增强效果。热分析表明,与纯环氧树脂相比,香蒲纤维复合材料的降解温度略有降低(-15%)。玻璃化转变温度确定在67至81℃范围内。