钌催化下伯酰胺和环状二肽的选择性氢化反应。
Selective hydrogenation of primary amides and cyclic di-peptides under Ru-catalysis.
机构信息
Department of Chemistry, Indian Institute of Science Education and Research (IISER) Tirupati, Tirupati - 517507, India.
出版信息
Chem Commun (Camb). 2020 Oct 15;56(82):12411-12414. doi: 10.1039/d0cc04550k.
PMID:32936149
Abstract
A ruthenium(ii)-catalyzed selective hydrogenation of challenging primary amides and cyclic di-peptides to their corresponding primary alcohols and amino alcohols, respectively, is reported. The hydrogenation reaction operates under mild and eco-benign conditions and can be scaled-up.
摘要
报道了一种钌（ii）催化的挑战性伯酰胺和环二肽的选择性氢化反应，分别得到相应的伯醇和氨基醇。该氢化反应在温和且环保的条件下进行，可以进行放大。
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