将硬币金属-NHC配合物引入七磷化物簇合物中。
Incorporation of coinage metal-NHC complexes into heptaphosphide clusters.
作者信息
Jo Minyoung, Li Jingbai, Dragulescu-Andrasi Alina, Rogachev Andrey Yu, Shatruk Michael
机构信息
Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306, USA.
Department of Cnmhemistry, Illinois Institute of Technology, 3101 South Dearborn St, Chicago, IL 60616, USA.
出版信息
Dalton Trans. 2020 Sep 29;49(37):12955-12959. doi: 10.1039/d0dt03119d.
Cu(i) and Au(i) ions, capped with an N-heterocyclic carbene (NHC), react with (TMS)3P7 (TMS = trimethyl-silyl) to afford an η4-coordinated anion [NHCDippCu-P7(TMS)]- and a neutral trinuclear complex (NHCDippAu)3P7. Protecting the P7 cage with the TMS groups is instrumental in controlling the course of these reactions.
用N-杂环卡宾（NHC）封端的Cu(i)和Au(i)离子与（TMS）3P7（TMS = 三甲基硅基）反应，生成一个η4配位阴离子[NHCDippCu-P7(TMS)]-和一个中性三核配合物（NHCDippAu）3P7。用TMS基团保护P7笼对于控制这些反应的进程至关重要。
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