Polimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia, Kimika Fakultatea, Euskal Herriko Unibertsitatea UPV/EHU & Donostia International Physics Center (DIPC) PK 1072, 20080 Donostia, Euskadi, Spain.
IKERBASQUE, Basque Foundation for Science, 48011 Bilbao, Spain.
Molecules. 2020 Oct 13;25(20):4668. doi: 10.3390/molecules25204668.
Various Lewis acid-Lewis base interactions are discussed as initiating chemical reactions and processes. For example, the hydrogen bond is often a preliminary stage of the proton transfer process or the tetrel and pnicogen bonds lead sometimes to the S2 reactions. There are numerous characteristics of interactions being first stages of reactions; one can observe a meaningful electron charge transfer from the Lewis base unit to the Lewis acid; such interactions possess at least partly covalent character, one can mention other features. The results of different methods and approaches that are applied in numerous studies to describe the character of interactions are presented here. These are, for example, the results of the Quantum Theory of Atoms in Molecules, of the decomposition of the energy of interaction or of the structure-correlation method.
讨论了各种路易斯酸碱相互作用作为引发化学反应和过程的因素。例如，氢键通常是质子转移过程的初始阶段，而碲属和磷属键有时会导致 S2 反应。存在许多相互作用作为反应初始阶段的特征；可以观察到路易斯碱单元向路易斯酸的有意义的电子电荷转移；这种相互作用具有至少部分共价性质，可以提及其他特征。这里介绍了在众多研究中应用于描述相互作用特征的不同方法和途径的结果。例如，分子中原子的量子理论、相互作用能量分解或结构相关方法的结果。
