Cavity ring-down spectroscopy of CO near = 2.06 μm: Accurate transition intensities for the Orbiting Carbon Observatory-2 (OCO-2) "strong band".

The = 2.06 μm absorption band of CO is widely used for the remote sensing of atmospheric carbon dioxide, making it relevant to many important top-down measurements of carbon flux. The forward models used in the retrieval algorithms employed in these measurements require increasingly accurate line intensity and line shape data from which absorption cross-sections can be computed. To overcome accuracy limitations of existing line lists, we used frequency-stabilized cavity ring-down spectroscopy to measure 39 transitions in the CO absorption band. The line intensities were measured with an estimated relative combined standard uncertainty of = 0.08 %. We predicted the -dependence of the measured intensities using two theoretical models: a one-dimensional spectroscopic model with Herman-Wallis rotation-vibration corrections, and a line-by-line dipole moment surface model [Zak et al. JQSRT 2016;177:31-42]. For the second approach, we fit only a single factor to rescale the theoretical integrated band intensity to be consistent with the measured intensities. We find that the latter approach yields an equally adequate representation of the fitted -dependent intensity data and provides the most physically general representation of the results. Our recommended value for the integrated band intensity equal to 7.183 × 10 cm molecule ± 6 × 10 cm molecule is based on the rescaled model and corresponds to a fitted scale factor of 1.0069 ± 0.0002. Comparisons of literature intensity values to our results reveal systematic deviations ranging from -1.16 % to +0.33 %.