Mi Guanyu, Lv Jian, Que Longcheng, Zhang Yi, Zhou Yun, Liu Zhongyuan
State Key Laboratory of Electronic Thin Film and Integrated Devices, University of Electronic Science and Technology of China, Cheng du, 610054, China.
China Electronics Technology Group Corporation, Chongqing Acoustic Optic Electronic CO.,LT, 401332, Chong qing, China.
Nanoscale Res Lett. 2021 Feb 27;16(1):38. doi: 10.1186/s11671-021-03499-x.
In this paper, a new preparation process of nanometer black silicon is proposed, by which high trapping optical Se-doped black silicon material is prepared by nanosecond pulsed laser ablation of high-resistance silicon coated with Se film in HF gas atmosphere. The results indicate that the average absorptivity of 400-2200 nm band before annealing is 96.81%, and the absorptivity maintains at 81.28% after annealing at 600 degrees. Meanwhile, black silicon prepared under the new technology is used in double four-quadrant photodetector, the results show that, at a reversed bias of 50 V, the average unit responsiveness is 0.528 A/W at 1060 nm and 0.102 A/W at 1180 nm, and the average dark current is 2 nA at inner quadrants and 8 nA at outer quadrants. The dual four-quadrant photodetector based on near-infrared enhanced black silicon has the advantages of high responsiveness, low dark current, fast response and low crosstalk, hence it is appropriate for a series of direction of applications, such as night vision detection and medical field.
本文提出了一种纳米黑硅的新制备工艺,通过在HF气体气氛中对涂覆有Se膜的高阻硅进行纳秒脉冲激光烧蚀,制备出高俘获光的Se掺杂黑硅材料。结果表明,退火前400 - 2200nm波段的平均吸收率为96.81%,600℃退火后吸收率保持在81.28%。同时,将新工艺制备的黑硅应用于双四象限光电探测器,结果表明,在50V反向偏压下,1060nm处的平均单位响应度为0.528A/W,1180nm处为0.102A/W,内象限平均暗电流为2nA,外象限为8nA。基于近红外增强黑硅的双四象限光电探测器具有响应度高、暗电流低、响应速度快和串扰低等优点,因此适用于夜视探测和医疗领域等一系列应用方向。