Rezaee Ehsan, Zhang Wei, Silva S Ravi P
Department of Electrical and Electronic Engineering, Advanced Technology Institute (ATI), University of Surrey, Guildford, Surrey, GU2 7XH, UK.
Small. 2021 Jun;17(25):e2008145. doi: 10.1002/smll.202008145. Epub 2021 May 14.
Organic-inorganic halide perovskite solar cells (PSCs) have shown a significant growth in power conversion efficiencies (PCEs) during last decade. Progress in device architecture and high-quality perovskite film fabrication has led to an incredible efficiency over 25% in close to a decade. Developments in solution-based thin film deposition techniques for perovskite layer preparation in PSCs provide low cost and ease of process for their manufacturing, making them a potential contender in future solar energy harvesting technologies. From small area single solar cells to large area perovskite solar modules, solvents play crucial roles in thin film quality and therefore, the device performance and stability. A comprehensive overview of solvent engineering toward achieving the highest qualities for perovskite light absorbing layers with various compositions and based on different fabrication processes is provided in this review. The mechanisms indicating the essential roles a solvent, or a solvent mixture can play to improve the crystallinity, uniformity, coverage and surface roughness of the perovskite films, are discussed. Finally, the role of solvent engineering in transferring from small area laboratory scale PSC fabrication to large area perovskite film deposition processes is explored.
在过去十年中,有机-无机卤化物钙钛矿太阳能电池(PSC)的功率转换效率(PCE)有了显著提高。器件结构和高质量钙钛矿薄膜制备技术的进步,使得在近十年内其效率达到了令人难以置信的25%以上。用于PSC中钙钛矿层制备的基于溶液的薄膜沉积技术的发展,为其制造提供了低成本和易于加工的特点,使其成为未来太阳能收集技术中的一个潜在竞争者。从小面积单太阳能电池到大面积钙钛矿太阳能模块,溶剂在薄膜质量以及器件性能和稳定性方面都起着至关重要的作用。本综述全面概述了溶剂工程,旨在通过各种组成和基于不同制造工艺来实现钙钛矿光吸收层的最高质量。讨论了表明溶剂或溶剂混合物在改善钙钛矿薄膜的结晶度、均匀性、覆盖率和表面粗糙度方面所起重要作用的机制。最后,探讨了溶剂工程在从小面积实验室规模的PSC制造向大面积钙钛矿薄膜沉积工艺转变中的作用。