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人类粪便污泥的等温干燥特性及动力学

Isothermal drying characteristics and kinetics of human faecal sludges.

作者信息

Somorin Tosin, Getahun Samuel, Septien Santiago, Mabbet Ian, Kolios Athanasios, Buckley Chris

机构信息

Chemical and Process Engineering, University of Strathclyde, Glasgow, G1 1XQ, UK.

Pollution Research Group, University of Kwazulu-Natal, Durban, 4041, South Africa.

出版信息

Gates Open Res. 2021 Apr 21;4:67. doi: 10.12688/gatesopenres.13137.2. eCollection 2020.

Abstract

Drying is an important step for the thermochemical conversion of solid fuels, but it is energy-intensive for treating highly moist materials. To inform the thermal treatment of faecal sludge (FS), this study investigated the drying characteristics and kinetics of various faecal wastes using thermogravimetric analysis and isothermal heating conditions. The findings show that FS from the anaerobic baffled reactor (ABR) and ventilated improved pit latrines (VIP) exhibit similar drying characteristics, with maximum drying rates at 0.04 mg/min during a constant rate period that is followed by a distinct falling rate period. On the contrary, fresh human faeces (HF) and FS from urine diversion dry toilets (UDDT) exhibited a falling rate period regime with no prior or intermittent constant rate periods. The absence of a constant rate period in these samples suggested limited amounts of unbound water that can be removed by dewatering and vice versa for VIP and ABR faecal sludges. The activation energies and effective moisture diffusivity for the sludges varied from 28 to 36 kJ/mol and 1.7·10 to 10·10 m /s at 55°C and sludge thickness of 3mm. The Page model was consistent in modelling the different sludges across all temperatures. These results presented in this study can inform the design and development of innovative drying methods for FS treatment.

摘要

干燥是固体燃料热化学转化的重要步骤,但对于处理高湿度物料来说能耗较大。为了为粪便污泥(FS)的热处理提供参考,本研究采用热重分析和等温加热条件,研究了各种粪便废物的干燥特性和动力学。研究结果表明,来自厌氧折流板反应器(ABR)和通风改良坑式厕所(VIP)的粪便污泥表现出相似的干燥特性,在恒速阶段最大干燥速率为0.04mg/min,随后是明显的降速阶段。相反,新鲜人粪(HF)和尿液分流干式厕所(UDDT)产生的粪便污泥呈现降速阶段模式,没有先前的或间歇的恒速阶段。这些样品中没有恒速阶段表明可通过脱水去除的自由水含量有限,而VIP和ABR粪便污泥则相反。在55°C和污泥厚度为3mm的条件下,污泥的活化能和有效水分扩散率分别在28至36kJ/mol和1.7·10 至10·10 m /s之间变化。Page模型在模拟所有温度下的不同污泥时是一致的。本研究提出的这些结果可为创新的粪便污泥处理干燥方法的设计和开发提供参考。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/92de/8135098/8c6444e603d3/gatesopenres-4-14477-g0000.jpg

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