Department of Chemical and Biological Engineering, Gachon University, Seongnam, Gyeonggi, 13120, Republic of Korea.
Small. 2021 Jul;17(28):e2100695. doi: 10.1002/smll.202100695. Epub 2021 Jun 10.
Power outages caused by the aging of high-voltage power facilities can cause significant economic and social damage. To prevent such problems, it is necessary to implement a widespread and sustainable monitoring system. Partial discharge (PD) is a preliminary symptom of power equipment aging accompanying the light, typically in the UV range. UVC (200-280 nm) is more useful than UVA and UVB because of low interference from the environment owing to its solar-blindness by the stratosphere. Therefore, to realize a wide-range and durable diagnosis system, it is necessary to develop sensors that can selectively detect UVC, while enabling mass production at low-cost and low power consumption. Here, a solution-processable photodiode sensor that is inexpensive, mass-producible, and self-powered with selective UVC detection is developed. The optoelectronic characteristics of photodiode consisting of organic p-polymer and inorganic n-ZnO nanoparticles are systematically studied to determine the optimum p-type polymer and its thickness. The device shows high-performance: fast response time (rise/fall time: 36.6/37.0 ms) and high spectral response in the UVC region (maximum responsivity of 20 mA W ) under self-powered operation. Furthermore, the practical application of the device to detect PD signals with a visual alarm system under UVC release conditions is demonstrated.
高压电力设施老化导致的停电会造成重大的经济和社会损失。为了防止此类问题,需要实施广泛且可持续的监测系统。局部放电(PD)是电力设备老化伴随的光现象的初步症状,通常处于紫外光范围。由于平流层的日盲性,UVC(200-280nm)比 UVA 和 UVB 更有用,因为它受环境干扰较小。因此,为了实现广泛且持久的诊断系统,有必要开发能够选择性检测 UVC 的传感器,同时能够以低成本和低功耗进行大规模生产。在这里,开发了一种廉价、可大规模生产且具有自供电功能的选择性 UVC 检测的溶液处理光电二极管传感器。系统地研究了由有机 p 型聚合物和无机 n-ZnO 纳米粒子组成的光电二极管的光电特性,以确定最佳的 p 型聚合物及其厚度。该器件在自供电操作下具有出色的性能:快速响应时间(上升/下降时间:36.6/37.0ms)和在 UVC 区域的高光谱响应(最大响应度为 20mA W )。此外,还展示了该器件在 UVC 释放条件下通过可视报警系统检测 PD 信号的实际应用。