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地质聚合物泡沫——它们会成为流行绝缘材料的可行替代品吗?——一种批判性观点。

Geopolymer Foams-Will They Ever Become a Viable Alternative to Popular Insulation Materials?-A Critical Opinion.

作者信息

Łach Michał

机构信息

Institute of Materials Engineering, Faculty of Materials Engineering and Physics, Cracow University of Technology, Jana Pawła II 37, 31-864 Cracow, Poland.

出版信息

Materials (Basel). 2021 Jun 25;14(13):3568. doi: 10.3390/ma14133568.

Abstract

Over the last several years, there has been a large increase in interest in geopolymer materials, which are usually produced from waste materials, and their applications. The possibilities of application of geopolymers seem to be unlimited, and they are used in almost all fields of technology. Their use as insulation materials appears promising due to their complete nonflammability and excellent strength. However, one limitation is their complex manufacturing process and lack of stability of the obtained geopolymer foams as well as difficulties in achieving such good insulation properties possessed by polyurethane foams, polystyrene, and wool. Hundreds of studies have already been performed on insulating geopolymer foams and various types of foaming agents, and their authors reported that foamed insulating geopolymers had a density starting from 200 kg/m and thermal conductivity from 0.04 W/mK. However, the repeatability of the obtained results on an industrial scale is questionable. It is still a challenge to obtain a geopolymer material with comparable properties as conventional insulation materials and to overcome the barriers associated with the successful implementation of geopolymer material as insulation in buildings and other applications on a mass scale. This paper provides a comprehensive review of the methods used for the production of foamed geopolymers and the best parameters obtained, as well as a summary of the most important information reported in the scientific literature. It also presents the results of a critical analysis of the feasibility of implementing this technology for mass deployment. In addition, the problems and limitations that are most often encountered with the implementation of geopolymer technology are discussed.

摘要

在过去几年中,人们对通常由废料生产的地质聚合物材料及其应用的兴趣大幅增加。地质聚合物的应用可能性似乎是无限的,并且它们几乎被用于所有技术领域。由于其完全不燃性和优异的强度,将它们用作绝缘材料似乎很有前景。然而,一个限制是它们复杂的制造过程、所得地质聚合物泡沫缺乏稳定性,以及难以实现聚氨酯泡沫、聚苯乙烯和羊毛所具有的如此良好的绝缘性能。已经对绝缘地质聚合物泡沫和各种类型的发泡剂进行了数百项研究,其作者报告说,发泡绝缘地质聚合物的密度从200 kg/m³起,热导率为0.04 W/(m·K)。然而,在工业规模上获得的结果的可重复性值得怀疑。要获得具有与传统绝缘材料相当性能的地质聚合物材料,并克服与在建筑物和其他应用中大规模成功应用地质聚合物材料作为绝缘材料相关的障碍,仍然是一个挑战。本文全面综述了用于生产发泡地质聚合物的方法和获得的最佳参数,以及科学文献中报道的最重要信息的总结。它还展示了对大规模部署该技术的可行性进行批判性分析的结果。此外,还讨论了实施地质聚合物技术时最常遇到的问题和限制。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7dec/8269725/1fa646d0e1f7/materials-14-03568-g001.jpg

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