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纳米 ZnO 和 FeO 磁性对活性炭 oak wood 去除甲基紫 2B 效率的影响。

Impact of ZnO and FeO magnetic nanoscale on the methyl violet 2B removal efficiency of the activated carbon oak wood.

机构信息

Polymer Research Laboratory, Department of Organic and Biochemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran.

Polymer Research Laboratory, Department of Organic and Biochemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran.

出版信息

Chemosphere. 2022 Jan;286(Pt 1):131632. doi: 10.1016/j.chemosphere.2021.131632. Epub 2021 Jul 21.

Abstract

In the current study, activated carbon oak wood (ACOW600) and modified activated carbon using ZnO (ACOW600/ZnO) and FeO (ACOW600/ZnO/FeO) nanoparticles were used to remove methyl violet 2B dye (MV2B) from aqueous solutions. ACOW was synthesized at different temperatures (300-700 °C), and then the maximum MV2B removal efficiency (92.76 %) was achieved using ACOW synthesized at 600 °C. The morphology and characteristics of ACOW600, ACOW600/ZnO, and ACOW600/ZnO/FeO were studied using surface analyzes. According to the results, the adsorbents indicated a high ability to absorb MV2B from liquid solution, and their kinetic behavior follows a pseudo-second-order kinetic. In addition, the equilibrium study revealed that the MV2B uptake by the ACOW600/ZnO/FeO magnetic nanocomposite followed the Freundlich model. In contrast, the Langmuir model described the MV2B adsorption process using ACOW600 and ACOW600/ZnO. The maximum adsorption capacity (q) of MV2B using ACOW600, ACOW600/ZnO, and ACOW600/ZnO/FeO was determined 26.16 mg g, 37.05 mg g, and 48.59 mg g, respectively, indicating that modification of ACOW600 led to improve its performance in removing MV2B. The enthalpy (ΔH), entropy (ΔG), and Gibbs free energy (ΔS) parameters revealed that the decontamination of MV2B using the studied adsorbents was exothermic and spontaneous. Also, random interactions of MV2B molecules and adsorbent surfaces were reduced during the adsorption process. Textile wastewater was significantly treated by ACOW600, ACOW600/ZnO, and ACOW600/ZnO/FeO adsorbents. The recycling of the adsorbents was demonstrated that the investigated adsorbents could be re-utilized many times in the MV2B removal process.

摘要

在当前的研究中,使用活性炭橡木(ACOW600)和用 ZnO(ACOW600/ZnO)和 FeO(ACOW600/ZnO/FeO)纳米粒子改性的活性炭来从水溶液中去除甲基紫 2B 染料(MV2B)。ACOW 是在不同温度(300-700°C)下合成的,然后使用在 600°C 下合成的 ACOW 达到最大的 MV2B 去除效率(92.76%)。使用表面分析研究了 ACOW600、ACOW600/ZnO 和 ACOW600/ZnO/FeO 的形态和特性。结果表明,吸附剂具有从液体溶液中吸附 MV2B 的高能力,并且它们的动力学行为遵循伪二阶动力学。此外,平衡研究表明,ACOW600/ZnO/FeO 磁性纳米复合材料对 MV2B 的吸收遵循 Freundlich 模型。相比之下,Langmuir 模型描述了使用 ACOW600 和 ACOW600/ZnO 吸附 MV2B 的过程。使用 ACOW600、ACOW600/ZnO 和 ACOW600/ZnO/FeO 确定的 MV2B 的最大吸附容量(q)分别为 26.16mg/g、37.05mg/g 和 48.59mg/g,表明 ACOW600 的改性导致其在去除 MV2B 方面的性能得到提高。焓(ΔH)、熵(ΔG)和吉布斯自由能(ΔS)参数表明,使用研究的吸附剂对 MV2B 的净化是放热和自发的。此外,在吸附过程中,MV2B 分子和吸附剂表面的随机相互作用减少。用 ACOW600、ACOW600/ZnO 和 ACOW600/ZnO/FeO 吸附剂对纺织废水进行了显著处理。证明了吸附剂的回收利用,表明所研究的吸附剂在 MV2B 去除过程中可以多次重复使用。

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