Horikawa Takashi, Yamazaki Masao, Matsuura Masashi, Sugimoto Satoshi
Frontier Research and Development Division, Aichi Steel Corporation, Tokai, Japan.
Department of Materials Science, Graduate School of Engineering, Tohoku University, Sendai, Japan.
Sci Technol Adv Mater. 2021 Sep 17;22(1):729-747. doi: 10.1080/14686996.2021.1944780. eCollection 2021.
Permanent magnets, and particularly rare earth magnets such as Nd-Fe-B, have attracted much attention because of their magnetic properties. There are two well-established techniques for obtaining sintered magnets and bonded Nd-Fe-B magnets. Powder metallurgy is used to obtain high-performance anisotropic sintered magnets. To produce bonded magnets, either melt-spinning or the hydrogenation, disproportionation, desorption, and recombination process is used to produce magnet powders, which are then mixed with binders. Since the development of Nd-Fe-B magnets, several kinds of intermetallic compounds have been reported, such as SmFeN and Sm(Fe,M) (M: Ti, V, etc.). However, it is difficult to apply a liquid-phase sintering process similar to the one used for Nd-Fe-B sintered magnets in order to produce high-performance Sm-Fe-based sintered magnets because of the low decomposition temperature of the compound and the lack of a liquid grain boundary phase like that in the Nd-Fe-B system. Therefore, bonded magnets are useful in the production of bulk magnets using these Sm-Fe-based compounds. This article reviews recent progress in our work on the development of high-performance bonded magnets using NdFeB and SmFeN compounds.
永磁体,尤其是钕铁硼等稀土磁体,因其磁性能而备受关注。有两种成熟的技术可用于制备烧结磁体和粘结钕铁硼磁体。粉末冶金用于制备高性能各向异性烧结磁体。为了生产粘结磁体,可采用熔体纺丝或氢化、歧化、脱氢和再复合工艺来生产磁粉,然后将其与粘结剂混合。自钕铁硼磁体问世以来,已报道了几种金属间化合物,如SmFeN和Sm(Fe,M)(M:Ti、V等)。然而,由于该化合物的分解温度较低,且缺乏像钕铁硼体系那样的液相晶界相,因此难以采用类似于钕铁硼烧结磁体的液相烧结工艺来制备高性能Sm-Fe基烧结磁体。因此,粘结磁体在使用这些Sm-Fe基化合物生产块状磁体方面很有用。本文综述了我们在使用NdFeB和SmFeN化合物开发高性能粘结磁体方面的最新进展。