Catalytic Oxidation of CO and Benzene over Metal Nanoparticles Loaded on Hierarchical MFI Zeolite.

In order to obtain highly active catalytic materials for oxidation of carbon monoxide and volatile organic compounds (VOCs), monometallic platinum, copper, and palladium catalysts were prepared by using of two types of ZSM-5 zeolite as supports-parent ZSM-5 and the same one treated by HF and NHF buffer solution. The catalyst samples, obtained by loading of platinum, palladium, and copper on ZSM-5 zeolite treated using HF and NHF buffer solution, were more active in the reaction of CO and benzene oxidation compared with catalyst samples containing untreated zeolite. The presence of secondary mesoporosity played a positive role in increasing the catalytic activity due to improved reactant diffusion. The only exception was the copper catalysts in the reaction of CO oxidation, in which case the catalyst, based on untreated ZSM-5 zeolite, was more active. In this specific case, the key role is played by the oxidative state of copper species loaded on the ZSM-5 zeolites.