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基于石墨烯的材料在水溶液中吸附去除铀。

Graphene-based materials for the adsorptive removal of uranium in aqueous solutions.

机构信息

Department of Civil & Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul 04763, Korea.

Department of Civil & Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul 04763, Korea.

出版信息

Environ Int. 2022 Jan;158:106944. doi: 10.1016/j.envint.2021.106944. Epub 2021 Oct 21.

Abstract

Ground water contamination by radioactive elements has become a critical issue that can pose significant threats to human health. Adsorption is the most promising approach for the removal of radioactive elements owing to its simplicity, effectiveness, and easy operation. Among the plethora of functional adsorbents, graphene oxide and its derivatives are recognized for their excellent potential as adsorbent with the unique 2D structure, high surface area, and intercalated functional groups. To learn more about their practical applicability, the procedures involved in their preparation and functionalization are described with the microscopic removal mechanism by GO functionalities across varying solution pH. The performance of these adsorbents is assessed further in terms of the basic performance metrics such as partition coefficient. Overall, this article is expected to provide valuable insights into the current status of graphene-based adsorbents developed for uranium removal with a guidance for the future directions in this research field.

摘要

地下水的放射性元素污染已成为一个关键问题,可能对人类健康造成重大威胁。吸附是去除放射性元素最有前途的方法,因为它简单、有效且易于操作。在众多功能吸附剂中,氧化石墨烯及其衍生物因其独特的 2D 结构、高表面积和插层官能团而被认为是具有优异吸附潜力的材料。为了更深入地了解其实际应用,本文介绍了其制备和功能化的过程,并描述了 GO 官能团在不同溶液 pH 值下的微观去除机制。此外,还根据分配系数等基本性能指标进一步评估了这些吸附剂的性能。总的来说,本文有望为基于石墨烯的吸附剂在去除铀方面的研究现状提供有价值的见解,并为该研究领域的未来方向提供指导。

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