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TiAl合金作为粘结剂对立方氮化硼复合材料的影响。

Effects of TiAl Alloy as a Binder on Cubic Boron Nitride Composites.

作者信息

Liu Yuxi, Zhang Wei, Peng Yingbo, Fan Guojiang, Liu Bin

机构信息

State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China.

出版信息

Materials (Basel). 2021 Oct 23;14(21):6335. doi: 10.3390/ma14216335.

Abstract

Owing to their extreme hardness, cubic boron nitride (cBN) composites are widely used in cutting applications. The performance of cBN composites is closely related to the characteristics of the binder. Therefore, novel binders must be developed to improve the performance of cBN composites. In the present work, TiAl intermetallics were used as binders to fabricate cBN composites by employing a high-temperature and high-pressure sintering method. The phase transformation, sintering reaction mechanism, thermal stability, and mechanical properties of the resultant cBN composites were investigated. It was found that during the sintering process, Ti atoms preferentially reacted with boron nitride particles, whereas Al atoms enriched and transformed into TiAl phases and formed cBN/AlN, AlB/TiN, and TiB/TiAl-layered structures eventually. The composites maintained good oxidation resistance at 1200 °C. A decrease in the particle size of the TiAl binder improved the uniformity of particle size distribution and increased the flexural strength of the composites.

摘要

由于其极高的硬度,立方氮化硼(cBN)复合材料被广泛应用于切削领域。cBN复合材料的性能与粘结剂的特性密切相关。因此,必须开发新型粘结剂以提高cBN复合材料的性能。在本工作中,采用高温高压烧结法,使用TiAl金属间化合物作为粘结剂来制备cBN复合材料。研究了所得cBN复合材料的相变、烧结反应机理、热稳定性和力学性能。结果发现,在烧结过程中,Ti原子优先与氮化硼颗粒反应,而Al原子富集并转变为TiAl相,最终形成cBN/AlN、AlB/TiN和TiB/TiAl层状结构。该复合材料在1200℃时保持良好的抗氧化性。TiAl粘结剂粒径的减小改善了粒径分布的均匀性,并提高了复合材料的抗弯强度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf38/8585436/c7181748e69b/materials-14-06335-g001.jpg

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