Department of Chemistry, Capital Normal University, Beijing 100048, China.
Beijing Key Laboratory for Optical Materials and Photonic Devices, Beijing 100048, China.
ACS Nano. 2021 Dec 28;15(12):18708-18741. doi: 10.1021/acsnano.1c05806. Epub 2021 Dec 9.
Laser-induced graphene (LIG) is produced rapidly by directly irradiating carbonaceous precursors, and it naturally exhibits as a three-dimensional porous structure. Due to advantages such as simple preparation, time-saving, environmental friendliness, low cost, and expanding categories of raw materials, LIG and its derivatives have achieved broad applications in sensors. This has been witnessed in various fields such as wearable devices, disease diagnosis, intelligent robots, and pollution detection. However, despite LIG sensors having demonstrated an excellent capability to monitor physical and chemical parameters, the systematic review of synthesis, sensing mechanisms, and applications of them combined with comparison against other preparation approaches of graphene is still lacking. Here, graphene-based sensors for physical, biological, and chemical detection are reviewed first, followed by the introduction of general preparation methods for the laser-induced method to yield graphene. The preparation and advantages of LIG, sensing mechanisms, and the properties of different types of emerging LIG-based sensors are comprehensively reviewed. Finally, possible solutions to the problems and challenges of preparing LIG and LIG-based sensors are proposed. This review may serve as a detailed reference to guide the development of LIG-based sensors that possess properties for future smart sensors in health care, environmental protection, and industrial production.
激光诱导石墨烯(LIG)通过直接辐照碳质前体快速制备,并且其天然呈现出三维多孔结构。由于制备简单、省时、环保、低成本和扩展原料种类等优势,LIG 及其衍生物在传感器领域得到了广泛的应用。这在可穿戴设备、疾病诊断、智能机器人和污染检测等各个领域都得到了证明。然而,尽管 LIG 传感器已经展示了监测物理和化学参数的出色能力,但对于它们的合成、传感机制以及与其他石墨烯制备方法的应用的系统综述,以及与其他制备方法的比较仍然缺乏。本文首先综述了用于物理、生物和化学检测的基于石墨烯的传感器,然后介绍了激光诱导方法制备石墨烯的一般方法。全面综述了 LIG 的制备和优点、传感机制以及不同类型新兴的基于 LIG 的传感器的性能。最后,提出了制备 LIG 和基于 LIG 的传感器的问题和挑战的可能解决方案。本综述可为指导具有未来医疗保健、环境保护和工业生产中智能传感器性能的基于 LIG 的传感器的发展提供详细参考。