Dong Jie, Yuan Shouqian, Sun Yongtao, Yang Shuangping, Xing Xiangdong, He Xiaomei
School of Metallurgical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China.
Shanxi Huaxiang Group Co., Ltd., Linfen 041600, China.
Materials (Basel). 2021 Nov 26;14(23):7219. doi: 10.3390/ma14237219.
In this paper, hot-dip aluminizing of ferrite nodular cast iron was carried out after treating liquid aluminum with different electrical pulse parameters. Compared with that of conventional hot-dip aluminizing, the coating structure of the treated sample did not change, the surface was smooth and continuous, and the solidification structure was more uniform. When high voltage and large capacitance were used to treat the liquid aluminum, the thickness and compactness of the coating surface layer increased. The thickness of the alloy layer decreased, and, the compactness and the micro hardness increased, so the electric pulse had a certain inhibition on the formation of the alloy layer. The growth kinetics of the alloy layer showed that the rate-time index decreased from 0.60 for the conventional sample to 0.38 for the electric pulse treated sample. The growth of the alloy layer was controlled by diffusion and interface reaction, but only by diffusion. The AC impedance and polarization curves of the coating showed that the corrosion resistance of hot-dip coating on nodular cast iron was improved by electric pulse treatment.
本文对经不同电脉冲参数处理的液态铝进行处理后,对铁素体球墨铸铁进行了热浸镀铝。与传统热浸镀铝相比,处理后样品的涂层结构未发生变化,表面光滑连续,凝固组织更均匀。当采用高电压和大电容处理液态铝时,涂层表面层的厚度和致密性增加。合金层厚度减小,致密性和显微硬度增加,因此电脉冲对合金层的形成有一定的抑制作用。合金层的生长动力学表明,速率-时间指数从传统样品的0.60降至电脉冲处理样品的0.38。合金层的生长由扩散和界面反应控制,但仅由扩散控制。涂层的交流阻抗和极化曲线表明,电脉冲处理提高了球墨铸铁热浸镀层的耐蚀性。