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关于用于水和废水处理的创新地质聚合物复合材料的最新综述

A State-of-the-Art Review on Innovative Geopolymer Composites Designed for Water and Wastewater Treatment.

作者信息

Luhar Ismail, Luhar Salmabanu, Abdullah Mohd Mustafa Al Bakri, Razak Rafiza Abdul, Vizureanu Petrica, Sandu Andrei Victor, Matasaru Petre-Daniel

机构信息

Department of Civil Engineering, Shri Jagdishprasad Jhabarmal Tibrewala University, Rajasthan 333001, India.

Center of Excellence Geopolymer and Green Technology (CEGeoGTech), Universiti Malaysia Perlis (UniMAP), Perlis 01000, Malaysia.

出版信息

Materials (Basel). 2021 Dec 4;14(23):7456. doi: 10.3390/ma14237456.

Abstract

There is nothing more fundamental than clean potable water for living beings next to air. On the other hand, wastewater management is cropping up as a challenging task day-by-day due to lots of new additions of novel pollutants as well as the development of infrastructures and regulations that could not maintain its pace with the burgeoning escalation of populace and urbanizations. Therefore, momentous approaches must be sought-after to reclaim fresh water from wastewaters in order to address this great societal challenge. One of the routes is to clean wastewater through treatment processes using diverse adsorbents. However, most of them are unsustainable and quite costly e.g. activated carbon adsorbents, etc. Quite recently, innovative, sustainable, durable, affordable, user and eco-benevolent Geopolymer composites have been brought into play to serve the purpose as a pretty novel subject matter since they can be manufactured by a simple process of Geopolymerization at low temperature, lower energy with mitigated carbon footprints and marvellously, exhibit outstanding properties of physical and chemical stability, ion-exchange, dielectric characteristics, etc., with a porous structure and of course lucrative too because of the incorporation of wastes with them, which is in harmony with the goal to transit from linear to circular economy, i.e., "one's waste is the treasure for another". For these reasons, nowadays, this ground-breaking inorganic class of amorphous alumina-silicate materials are drawing the attention of the world researchers for designing them as adsorbents for water and wastewater treatment where the chemical nature and structure of the materials have a great impact on their adsorption competence. The aim of the current most recent state-of-the-art and scientometric review is to comprehend and assess thoroughly the advancements in geo-synthesis, properties and applications of geopolymer composites designed for the elimination of hazardous contaminants viz., heavy metal ions, dyes, etc. The adsorption mechanisms and effects of various environmental conditions on adsorption efficiency are also taken into account for review of the importance of Geopolymers as most recent adsorbents to get rid of the death-defying and toxic pollutants from wastewater with a view to obtaining reclaimed potable and sparkling water for reuse offering to trim down the massive crisis of scarcity of water promoting sustainable water and wastewater treatment for greener environments. The appraisal is made on the performance estimation of Geopolymers for water and wastewater treatment along with the three-dimensional printed components are characterized for mechanical, physical and chemical attributes, permeability and Ammonium (NH) ion removal competence of Geopolymer composites as alternative adsorbents for sequestration of an assortment of contaminants during wastewater treatment.

摘要

对于生物来说,除了空气,没有什么比清洁的饮用水更重要的了。另一方面,由于大量新型污染物的不断增加,以及基础设施和法规的发展无法跟上人口增长和城市化迅速发展的步伐,废水管理正日益成为一项具有挑战性的任务。因此,必须寻求重大方法从废水中回收淡水,以应对这一巨大的社会挑战。其中一条途径是使用各种吸附剂通过处理工艺净化废水。然而,它们中的大多数是不可持续的且成本相当高,例如活性炭吸附剂等。最近,创新、可持续、耐用、经济实惠、对用户和环境友好的地质聚合物复合材料开始发挥作用,作为一个相当新颖的主题,因为它们可以通过低温、低能耗且碳足迹较小的简单地质聚合过程制造,并且奇妙的是,它们具有出色的物理和化学稳定性、离子交换、介电特性等性能,具有多孔结构,而且由于与废物结合,成本也很划算,这与从线性经济向循环经济转变的目标相一致,即“一人之废,他人之宝”。出于这些原因,如今,这种开创性的无机类无定形铝硅酸盐材料正吸引着全球研究人员的关注,他们将其设计为用于水和废水处理的吸附剂,其中材料的化学性质和结构对其吸附能力有很大影响。当前最新的前沿和科学计量学综述的目的是全面理解和评估用于去除有害污染物(即重金属离子、染料等)的地质聚合物复合材料在地质合成、性能和应用方面的进展。在综述中还考虑了各种环境条件对吸附效率的吸附机制和影响,以了解地质聚合物作为最新吸附剂从废水中去除致命和有毒污染物的重要性,从而获得可再利用的再生饮用水和优质水,以减少严重的水资源短缺危机,促进可持续的水和废水处理,实现更绿色的环境。对地质聚合物在水和废水处理方面的性能评估进行了评价,同时对三维打印部件的机械、物理和化学属性、渗透性以及地质聚合物复合材料去除铵(NH)离子的能力进行了表征,这些复合材料可作为替代吸附剂,在废水处理过程中螯合各种污染物。

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