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致密油藏CO低界面张力粘弹性流体协同驱替

CO-Low Interfacial Tension Viscoelastic Fluid Synergistic Flooding in Tight Reservoirs.

作者信息

Chen Longlong, Liao Xinwei, Tang Shanfa, Feng Shuyun, Tang Ruijia, Jiang Shaojing, Dong Yuanwu

机构信息

State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum, Beijing 102249, China.

Yanchang Petroleum Group CO., Ltd., Xian, Shanxi 710075, China.

出版信息

ACS Omega. 2022 Feb 11;7(7):6271-6279. doi: 10.1021/acsomega.1c06803. eCollection 2022 Feb 22.

Abstract

Tight oil reservoirs have poor physical properties, insufficient formation energy, and low natural productivity. CO flooding is an important technical mean that enhances the oil recovery of dense reservoirs and achieves effective CO sequestration, but strong heterogeneity of the tight oil reservoir usually results in gas channeling and poor enhanced oil recovery effect. The existing methods to prevent gas channeling are mainly to use the small-molecule amine system and the polymer gel system to plug fracture and high permeability channels. The small-molecular amine system has low flash points and pollutes the environment and the polymer gel has poor injectivity and great damage to the formation, which limit their large-scale application. Therefore, a new viewpoint of CO-low interfacial tension viscoelastic fluid synergistic flooding for enhanced oil recovery in a tight oil reservoir was made. The performance of low interfacial tension viscoelastic fluid (GOBT) was studied. The injectivity and oil displacement effect of CO-GOBT synergistic flooding were evaluated, and the mechanism of CO-GOBT synergistic flooding was discussed. The experimental results showed that 0.4% GOBT is a low interfacial tension viscoelastic fluid, which has strong adaptability to the salinity water of tight oil reservoirs (6788-80,000 mg/L), good viscosity stability at different pHs, excellent capacity to emulsify crude oil, and the ability to improve reservoir water wettability. CO alternating 0.4% GOBT flooding has good injection ability in cores ( = 0.249 mD), and injecting 0.4% GOBT can effectively increase the injection pressure of subsequent CO flooding. CO alternating 0.4% GOBT flooding can effectively improve water flooding recovery in tight sandstone reservoirs, which is better than CO flooding and 0.4% GOBT flooding in both homogeneous and heterogeneous conditions. The mechanisms of CO alternating 0.4% GOBT flooding to enhance the oil recovery include that GOBT and CO foam block high permeability layers, shunt and sweep low permeability layers, and GOBT emulsify and wash oil. CO partially dissolving in GOBT synergistically enhances the core water wettability, which improves GOBT injectability, emulsification, and stripping ability to residual oil.

摘要

致密油藏物性差、地层能量不足、自然产能低。CO驱是提高致密油藏采收率和实现有效CO封存的重要技术手段,但致密油藏的强非均质性通常会导致气窜,提高采收率效果不佳。现有的防止气窜的方法主要是使用小分子胺体系和聚合物凝胶体系封堵裂缝和高渗通道。小分子胺体系闪点低、污染环境,聚合物凝胶注入性差、对地层伤害大,限制了它们的大规模应用。因此,提出了一种CO-低界面张力粘弹性流体协同驱替提高致密油藏采收率的新观点。研究了低界面张力粘弹性流体(GOBT)的性能。评价了CO-GOBT协同驱替的注入性和驱油效果,并探讨了CO-GOBT协同驱替的机理。实验结果表明,0.4%GOBT是一种低界面张力粘弹性流体,对致密油藏盐水(6788-80000mg/L)具有较强的适应性,在不同pH值下具有良好的粘度稳定性,具有优异的乳化原油能力,以及改善储层水润湿性的能力。CO交替注入0.4%GOBT在岩心(渗透率=0.249mD)中具有良好的注入能力,注入0.4%GOBT能有效提高后续CO驱的注入压力。CO交替注入0.4%GOBT能有效提高致密砂岩油藏的水驱采收率,在均质和非均质条件下均优于CO驱和0.4%GOBT驱。CO交替注入0.4%GOBT提高采收率的机理包括GOBT和CO泡沫封堵高渗层,分流和波及低渗层,以及GOBT乳化和洗油。CO部分溶解在GOBT中协同增强岩心水润湿性,提高GOBT的注入性、乳化性和对残余油的剥离能力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/38dd/8867575/041e92e6feea/ao1c06803_0002.jpg

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