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用于无创测温的铝掺杂钛酸盐荧光粉上转换发光的定制

Tailoring of upconversion luminescence of Alengineered titanate phosphor for non-invasive thermometry.

作者信息

Pattnaik Sasank, Rai Vineet Kumar

机构信息

Laser and Spectroscopy Laboratory, Department of Physics, Indian Institute of Technology (Indian School of Mines), Dhanbad-826004, Jharkhand, India.

出版信息

Methods Appl Fluoresc. 2022 Apr 7;10(3). doi: 10.1088/2050-6120/ac60a9.

Abstract

The ability of rare-earth-doped ferroelectric oxides to achieve outstanding upconversion (UC) performances under NIR irradiation despite possessing intrinsic electric properties drives researchers all over the globe to work in this field. The structural and spectroscopic characteristics of the BiTiOphosphor integrated with Er, Yb, and Alhave been thoroughly investigated in this study. The considerable increase in UC emission ∼three times caused by the addition of Alions has been observed and discussed. The processes connected with the UC emission related to the pump power variation have been realized using the rate law equation. Aside from having high sensitivity of 0.011 Kat room temperature, the prepared phosphor possesses excellent thermal stability, i.e., it retains ∼73% of its initial intensity with the addition of Alions.

摘要

尽管具有本征电学性质,但稀土掺杂铁电氧化物在近红外辐射下仍能实现出色的上转换(UC)性能,这驱使全球的研究人员投身于该领域的研究。本研究对掺有铒、镱和铝的钛酸铋荧光粉的结构和光谱特性进行了深入研究。观察并讨论了由于添加铝离子导致上转换发射显著增加约三倍的现象。利用速率定律方程实现了与泵浦功率变化相关的上转换发射过程。所制备的荧光粉除了在室温下具有0.011 K的高灵敏度外,还具有出色的热稳定性,即添加铝离子后仍保留其初始强度的约73%。

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