Tominaga Yusuke, Takeda Kazuyuki
Division of Chemistry, Graduate School of Science, Kyoto University, 606-8502 Kyoto, Japan.
Analyst. 2022 May 3;147(9):1847-1852. doi: 10.1039/d2an00220e.
Electro-mechano-optical (EMO) NMR, an emerging NMR detection technique with signal upconversion from radiofrequency to optical regimes a SiN nanomembrane, has become compatible with NMR analysis in chemistry using a highly homogeneous but space-limited magnetic field provided by a superconducting magnet (SCM) by development of a compact EMO NMR probe operational inside the SCM bore. Optical C NMR signal detection following H-C magnetization transfer in liquid benzene is demonstrated.
机电光(EMO)核磁共振(NMR)是一种新兴的NMR检测技术,可实现信号从射频到光频段的上转换,通过在超导磁体(SCM)内部操作的紧凑型EMO NMR探头的开发,利用SCM提供的高度均匀但空间有限的磁场,已与化学中的NMR分析兼容。本文展示了在液态苯中进行H-C磁化转移后对碳-13(C)NMR信号的光学检测。