化学钟在材料设计中的应用：沸石咪唑酯骨架-8 的化学程控合成。
Application of a chemical clock in material design: chemically programmed synthesis of zeolitic imidazole framework-8.
机构信息
Department of Physics, Institute of Physics, Budapest University of Technology and Economics, H- 1111, Műegyetem rkp 3., Budapest, Hungary.
MTA-BME Condensed Matter Research Group, Budapest University of Technology and Economics, H-1111, Műegyetem rkp 3., Budapest, Hungary.
出版信息
Chem Commun (Camb). 2022 May 10;58(38):5777-5780. doi: 10.1039/d2cc01139e.
Here we show a time-programmed and autonomous synthesis of zeolitic imidazole framework-8 (ZIF-8) using a methylene glycol-sulfite clock reaction. The induction period of the driving clock reaction, thus, the appearance of the ZIF-8 can be adjusted by the initial concentration of one reagent of the chemical clock. The autonomously synthesized ZIF-8 showed excellent morphology and crystallinity.
在这里，我们展示了一种使用亚甲基二醇-亚硫酸盐时钟反应的沸石咪唑骨架-8（ZIF-8）的时间程序和自主合成。通过化学时钟的一种试剂的初始浓度，可以调节驱动时钟反应的诱导期，从而调节 ZIF-8 的出现。自主合成的 ZIF-8 表现出优异的形态和结晶度。
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