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通过植入钒酸锶提高石墨相氮化碳中的电荷分离和氮空位以实现高效光催化还原六价铬

Boosting charge separation and nitrogen vacancies in graphitic carbon nitride by implanted strontium vanadate for highly efficient photocatalytic reduction of hexavalent chromium.

作者信息

Zhou Yuzhi, Kang Shi-Zhao, Qin Lixia, Li Xiangqing

机构信息

Shanghai Institute of Technology China

出版信息

RSC Adv. 2021 Apr 29;11(26):16034-16039. doi: 10.1039/d1ra01489g. eCollection 2021 Apr 26.

Abstract

Strontium vanadate nanoparticles embedded graphitic carbon nitride (g-CN/SrVO) was facilely prepared a hydrothermal method. It was shown that the SrVO nanoparticles implanted into g-carbon nitride had a small size and high distribution. Importantly, compared with some other photocatalysts, the as-prepared g-CN/SrVO nanohybrid showed excellent photocatalytic activity for reduction of Cr(vi), and as high as 99% efficiency for Cr(vi) reduction (100 mg L) was reached within 8 min. Moreover, its activity was hardly changed after five cycles, demonstrating that the developed g-CN/SrVO nanohybrid was highly stable and promising an efficacious disposal of Cr(vi) in water. It was confirmed that the improved charge separation owing to more nitrogen vacancies in the hybrid was the main reason for the improved performance of the g-CN-SrVO nanohybrid.

摘要

通过水热法轻松制备了嵌入钒酸锶纳米颗粒的石墨相氮化碳(g-CN/SrVO)。结果表明,植入到石墨相氮化碳中的钒酸锶纳米颗粒尺寸小且分布均匀。重要的是,与其他一些光催化剂相比,所制备的g-CN/SrVO纳米杂化物对Cr(Ⅵ)的还原表现出优异的光催化活性,在8分钟内对Cr(Ⅵ)(100 mg/L)的还原效率高达99%。此外,经过五个循环后其活性几乎没有变化,这表明所开发的g-CN/SrVO纳米杂化物具有高度稳定性,有望有效处理水中的Cr(Ⅵ)。证实了由于杂化物中更多的氮空位导致电荷分离得到改善是g-CN-SrVO纳米杂化物性能提高的主要原因。

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