Highly efficient visible light active Cu-ZnO/S-g-CN nanocomposites for efficient photocatalytic degradation of organic pollutants.

The photocatalytic activity of photocatalysts is severely hampered by limited visible light harvesting and unwanted fast recombination of photogenerated e and h. In the current study, the photocatalytic efficiency of Cu-ZnO/S-g-CN (CZS) nanocomposites was investigated against MB dye. The composite materials were designed chemical co-precipitation method and characterised by important analytical techniques. Distinctive heterojunctions developed between S-g-CN and Cu-ZnO in the CZS composite were revealed by TEM. The synthesized composites exhibit a huge number of active sites, a large surface area, a smaller size and better visible light absorption. The considerable enhancement in the photocatalytic activity of CZS nanocomposites might be accredited to the decay in the e-h pair recombination rate and a red shift in the visible region, as observed by PL and optical analysis, respectively. Furthermore, the metal (Cu) doping into the S-g-CN/ZnO matrix created exemplary interfaces between ZnO and S-g-CN, and maximized the photocatalytic activity of CZS nanocomposites. In particular, CZS nanocomposites synthesized by integrating 25% S-g-CN with 4% Cu-ZnO (CZS-25 NCs) exhibited the 100% photocatalytic degradation of MB in 60 minutes under sunlight irradiation. After six cycles, the photocatalytic stability of CZS-25 NCs was excellent. Likewise, a plausible MB degradation mechanism is proposed over CZS-25 NCs based on photoluminescence and reactive species scavenger test observation. The current research supports the design of novel composites for the photocatalytic disintegration of organic contaminants.