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用于高效潜指纹识别时间门控荧光的新型有机-无机杂化粉末SrGaO:Mn-乙基纤维素

Novel organic-inorganic hybrid powder SrGaO:Mn-ethyl cellulose for efficient latent fingerprint recognition time-gated fluorescence.

作者信息

Lai Jun'an, Long Zhangwen, Qiu Jianbei, Zhou Dacheng, Wang Qi, Yang Yong, Hu Songhan, Wang Zhe, Zhang Ke

机构信息

College of Materials Science and Engineering, Kunming University of Science and Technology Kunming 650093 China

Key Lab. of Advanced Materials of Yunnan Province Kunming 650093 China.

出版信息

RSC Adv. 2020 Feb 26;10(14):8233-8243. doi: 10.1039/d0ra00138d. eCollection 2020 Feb 24.

Abstract

Latent fingerprints (LFPs) are important evidence in crime scenes and forensic investigations, but they are invisible to the naked eye. In this work, a novel fluorescent probe was developed by integrating a narrow-band-emitting green afterglow phosphor, SrGaO:Mn (SGO:Mn), and ethyl cellulose (EC) for the efficient visualization of LFPs. The hydrophobic interactions between the powder and lipid-rich LFPs made the ridge structures more defined and easily identifiable. The background fluorescence of the substrates was completely avoided because of the time-gated fluorescence of the afterglow phosphor. All the three levels of LFP degrees were clearly imaged due to the high sensitivity. Moreover, the SGO:Mn-EC powder was highly stable in neutral, acidic, and alkaline environments. In addition, 60 day-aged LFPs were successfully visualized by the powder. All performances showed that this strategy for LFP recognition has merits such as low cost, non-destructive nature, reliability, superior universality, and legible details. Together, these results show the great application prospects of this powder in forensic identification and criminal investigation.

摘要

潜在指纹(LFPs)是犯罪现场和法医调查中的重要证据,但肉眼不可见。在这项工作中,通过将窄带发射绿色余辉荧光粉SrGaO:Mn(SGO:Mn)与乙基纤维素(EC)相结合,开发了一种新型荧光探针,用于高效可视化潜在指纹。粉末与富含脂质的潜在指纹之间的疏水相互作用使脊状结构更加清晰,易于识别。由于余辉荧光粉的时间门控荧光,完全避免了底物的背景荧光。由于高灵敏度,所有三个潜在指纹程度级别都能清晰成像。此外,SGO:Mn-EC粉末在中性、酸性和碱性环境中高度稳定。此外,该粉末成功地可视化了60天龄的潜在指纹。所有性能表明,这种潜在指纹识别策略具有成本低、无损、可靠、通用性强和细节清晰等优点。总之,这些结果表明该粉末在法医鉴定和刑事调查中具有广阔的应用前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/220c/9049934/94290aba603c/d0ra00138d-s1.jpg

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