Vujić Mario, Lušić Dražen, Bošnir Jasna, Pezo Lato L, Kuharić Željka, Lasić Dario, Šabarić Jasenka, Barušić Lidija, Lušić Darija Vukić
Directorate for Climate Activities, Ministry of Economy and Sustainable Development, 10000 Zagreb, Croatia.
Department of Environmental Health, Faculty of Medicine, University of Rijeka, 51000 Rijeka, Croatia.
Foods. 2022 Apr 28;11(9):1279. doi: 10.3390/foods11091279.
The aim of this study was to determine the quantity of particular toxic metals (Pb, Cd, As, Hg) and micronutrients (Cr, Fe, Co, Ni, Cu, Zn, Se) in the recommended daily dose of 51 food supplements based on beehive products. Samples taken from the Croatian market were submitted for the identification/quantification of studied metals and micronutrients. It was carried out by means of inductively coupled plasma mass spectrometry (ICP-MS). Eleven samples (21.57%) showed an increased concentration of total arsenic, three samples (5.88%) contained an increased concentration of total iron, and eight samples (15.68%) had an increased concentration of total nickel. Three samples (5.88%) contained an increased concentration of zinc, while one sample (1.96%) contained an increased concentration of selenium. Increased levels of certain toxic metals and micronutrients do not pose a danger to human health because the amount identified was less than what can cause toxic effects in humans. All other analysed metals and micronutrients fell within the defined literature values. Despite certain increases in particular parameters, all samples met the established toxicity criteria. This study evidenced their safety if consumed in the recommended daily dose.
本研究的目的是测定51种基于蜂产品的食品补充剂推荐日剂量中特定有毒金属(铅、镉、砷、汞)和微量营养素(铬、铁、钴、镍、铜、锌、硒)的含量。从克罗地亚市场采集的样本被送去鉴定/定量所研究的金属和微量营养素。这是通过电感耦合等离子体质谱法(ICP-MS)进行的。11个样本(21.57%)显示总砷浓度升高,3个样本(5.88%)总铁浓度升高,8个样本(15.68%)总镍浓度升高。3个样本(5.88%)锌浓度升高,而1个样本(1.96%)硒浓度升高。某些有毒金属和微量营养素水平的升高对人体健康不构成危险,因为所鉴定的量低于会对人体产生毒性作用的量。所有其他分析的金属和微量营养素都在规定的文献值范围内。尽管某些参数有所升高,但所有样本均符合既定的毒性标准。这项研究证明,如果按照推荐日剂量食用,它们是安全的。