Zhang Bing, Tan Zhiqiang, Zhang Yinhu, Liu Qingquan, Li Qianxia, Li Gen
Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Materials Science and Engineering, Hunan University of Science and Technology, Taoyuan Street, Xiangtan 411201, China.
Polymers (Basel). 2022 May 6;14(9):1900. doi: 10.3390/polym14091900.
Microporous organic polymers (MOPs) were prepared by condensation reactions from substituent-group-free carbazole and pyrrole with 1,1'-ferrocenedicarboxaldehyde without adding any catalysts. The resultant MOPs were insoluble in common solvent and characterized by FTIR, XPS, TGA and SEM. An N adsorption test showed that the obtained polymers PFcMOP and CFcMOP exhibited Brunauer-Emmett-Teller (BET) surface areas of 48 and 105 m g, respectively, and both polymers possessed abundant micropores. The MOPs with a nitrogen and ferrocene unit could be potentially applied in degrading dye with high efficiency.
通过无取代基咔唑和吡咯与1,1'-二茂铁二甲醛的缩合反应制备了微孔有机聚合物（MOPs），且未添加任何催化剂。所得的MOPs不溶于常见溶剂，并通过傅里叶变换红外光谱（FTIR）、X射线光电子能谱（XPS）、热重分析（TGA）和扫描电子显微镜（SEM）进行了表征。氮气吸附测试表明，所制备的聚合物PFcMOP和CFcMOP的比表面积分别为48和105 m²/g，且两种聚合物均具有丰富的微孔。含有氮和二茂铁单元的MOPs具有高效降解染料的潜在应用价值。
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