Aramid Fibers Modulated Polyethylene Separator as Efficient Polysulfide Barrier for High-Performance Lithium-Sulfur Batteries.

The separators with high absorbability of polysulfides are essential for improving the electrochemical performance of lithium-sulfur (Li-S) batteries. Herein, the aramid fibers coated polyethylene (AF-PE) films are designed by roller coating, the high polarity of AFs can strongly increase the binding force at AF/PE interfaces to guarantee the good stability of the hybrid film. As confirmed by the microscopic analysis, the AF-PE-6 film with the nanoporous structure exhibits the highest air permeability by the optimal coating content of AFs. The high absorbability of polysulfides for AF-PE-6 film can effectively hinder the migration of polysulfides and alleviate the shuttle effect of the Li-S battery. AF-PE-6 cell shows the specific capacity of 661 mAh g at 0.1 C. After 200 charge/discharge cycles, the reversible specific capacity is 542 mAh g with the capacitance retention of 82%, implying the excellent stability of AF-PE-6. The enhanced cell performance is attributed to the porous architecture of the aramid layer for trapping the dissolved sulfur-containing species and facilitating the charge transfer, as confirmed by SEM and EDS after 200 cycles. This work provides a facile way to construct the aramid fiber-coated separator for the inhibition of polysulfides in the Li-S battery.